methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Base Information

Chemical Name:methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside
CAS No.:187109-48-4
Molecular Formula:C₆₀H₆₆ClNO₂₃
Molecular Weight:1204.63
Hs Code.:

methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Synonyms:methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Suppliers and Price of methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

There total 8 articles about methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 55697-53-5
methyl 2,4,6-tri-O-benzyl-β-D-galactopyranoside

: 187109-47-3
2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl trichloroacetimidate

: 187109-48-4
methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -45 ℃; for 2h;
DOI:10.1016/S0008-6215(96)00236-4

Reference yield:

: 117253-00-6
2-(trimethylsilyl)ethyl 4,6-O-benzylidene-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 187109-48-4
methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 8 steps

1: 78 percent / NaCNBH₃, 3A molecular sieves / tetrahydrofuran; diethyl ether / 2 h / 0 °C

2: 72 percent / Hg(CN)2 / toluene; nitromethane / 12 h / Ambient temperature

3: 98 percent / pyridine

4: 63 percent / H₂ / Pd/C / methanol; acetic acid / 16 h / 1551.4 Torr

5: 91 percent / 2,6-lutidine / CH₂Cl₂

6: 93 percent / pyridine; trifluoroacetic acid / 2 h / Ambient temperature

7: 78 percent / K₂CO₃ / CH₂Cl₂ / 4 h / Ambient temperature

8: 94 percent / SiMe₃OTf, 4AMS / CH₂Cl₂ / 2 h / -45 °C

With 2,6-dimethylpyridine; trimethylsilyl trifluoromethanesulfonate; 3 A molecular sieve; hydrogen; mercury(II) cyanide; sodium cyanoborohydride; potassium carbonate; palladium on activated charcoal; In tetrahydrofuran; pyridine; methanol; diethyl ether; nitromethane; dichloromethane; acetic acid; toluene; trifluoroacetic acid;
DOI:10.1016/S0008-6215(96)00236-4

Reference yield:

: 174314-11-5
2-(trimethylsilyl)ethyl-6-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 187109-48-4
methyl 2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl-(1->4)-3-O-acetyl-6-O-chloroacetyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-β-D-galactopyranoside

Guidance literature:: Multi-step reaction with 7 steps

1: 72 percent / Hg(CN)2 / toluene; nitromethane / 12 h / Ambient temperature

2: 98 percent / pyridine

3: 63 percent / H₂ / Pd/C / methanol; acetic acid / 16 h / 1551.4 Torr

4: 91 percent / 2,6-lutidine / CH₂Cl₂

5: 93 percent / pyridine; trifluoroacetic acid / 2 h / Ambient temperature

6: 78 percent / K₂CO₃ / CH₂Cl₂ / 4 h / Ambient temperature

7: 94 percent / SiMe₃OTf, 4AMS / CH₂Cl₂ / 2 h / -45 °C

With 2,6-dimethylpyridine; trimethylsilyl trifluoromethanesulfonate; hydrogen; mercury(II) cyanide; potassium carbonate; palladium on activated charcoal; In pyridine; methanol; nitromethane; dichloromethane; acetic acid; toluene; trifluoroacetic acid;
DOI:10.1016/S0008-6215(96)00236-4