1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

Base Information

Chemical Name:1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit
CAS No.:104976-22-9
Molecular Formula:C₂₂H₂₃F₃O₇S
Molecular Weight:488.482
Hs Code.:

Synonyms:1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

Suppliers and Price of 1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

There total 1 articles about 1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 76139-13-4
1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-myo-inosit

: 104976-22-9
1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

Guidance literature:: With pyridine; In dichloromethane; 1.) 5 min, -40 deg C; 2.) 3 h, room temp.;

Reference yield: 82.0%

: 104976-22-9
1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

: 104976-23-0
1D-1,2-Anhydro-6-O-benzoyl-4,5-di-O-benzyl-3-O-methyl-chiro-inosit

Guidance literature:: In N,N-dimethyl-formamide; at 0 ℃; for 1h;

Reference yield:

: 104976-22-9
1L-1,2-Anhydro-4,5-di-O-benzyl-6-O-methyl-3-O-<(trifluormethyl)sulfonyl>-myo-inosit

: 104976-30-9
2L-(2,4,5/3,6)-3,4,5-Tri-O-benzyl-6-O-<(2-methoxyethoxy)methyl>-2-O-methyl-1-C-methylen-2,3,4,5,6-cyclohexanpentol

Guidance literature:: Multi-step reaction with 8 steps

1: 82 percent / dimethylformamide / 1 h / 0 °C

2: 85 percent / NaOMe (1M) / methanol / 3 h

3: 84 percent / NaH / dimethylformamide / 0.83 h / 0 °C

4: 79 percent / Et₂O-BF₃ / CH₂Cl₂ / 4 h / Ambient temperature

5: 84 percent / NEt(iPr)2 / CH₂Cl₂

6: 67 percent / AcOH (95percent), AcONa / PdCl₂ / 12 h

7: 1.) (COCl)2, DMSO; 2.) NEt(iPr)2 / 1.) CH₂Cl₂, 30 min, -78 deg C; 2.) CH₂Cl₂, 30 min, room temp.

8: 1.) n-BuLi / 1.) THF, hexane; 2.) 12 h, room temp.

With n-butyllithium; oxalyl dichloride; boron trifluoride diethyl etherate; sodium methylate; sodium acetate; sodium hydride; acetic acid; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; palladium dichloride; In methanol; dichloromethane; N,N-dimethyl-formamide;