Gold(1+), dichloro(1,10-phenanthroline-κN1,κN10)-, chloride (1:1), (SP-4-2)-

Base Information

• Chemical Name: Gold(1+), dichloro(1,10-phenanthroline-κN1,κN10)-, chloride (1:1), (SP-4-2)-
• CAS No.: 14910-99-7
• Molecular Formula: C₁₂H₈AuCl₂N₂*Cl
• Molecular Weight: 483.534
• Mol file: 14910-99-7.mol

Synonyms:1,2-dichloro(o-phenanthroline)gold(III) chloride

Chemical Property of Gold(1+), dichloro(1,10-phenanthroline-κN1,κN10)-, chloride (1:1), (SP-4-2)-

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Gold(1+), dichloro(1,10-phenanthroline-κN1,κN10)-, chloride (1:1), (SP-4-2)-

There total 6 articles about Gold(1+), dichloro(1,10-phenanthroline-κN1,κN10)-, chloride (1:1), (SP-4-2)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,10-Phenanthroline (66-71-7) + hydrogen tetrachloroaurate(III) tetrahydrate → 1,2-dichloro(o-phenanthroline)gold(III) chloride (14910-99-7)

Guidance literature:

In ethanol; EtOH soln. of phen added to EtOH soln. of Au complex under stirring, stirred under reflux for 4 h; ppt. filtered, washed (EtOH), dried in air; elem. anal.;

DOI:10.1016/j.molcata.2011.03.008

Reference yield: 60.0%

1,10-Phenanthroline (66-71-7) + chloroauric acid → 1,2-dichloro(o-phenanthroline)gold(III) chloride (14910-99-7)

Guidance literature:

In water; acetonitrile; addn. of 10% excess of phenanthroline in MeCN to aq. soln. of HAuCl4; pptn., stirring for 30 min; filtration, washing with acetone and ether, drying in vac.;

DOI:10.1134/S1070363206060016

Reference yield: 31.0%

1,10-Phenanthroline (66-71-7) + gold(III) tetrachloride trihydrate → 1,2-dichloro(o-phenanthroline)gold(III) chloride (14910-99-7)

Guidance literature:

In ethanol; at 72 ℃; for 0.5h;

DOI:10.1039/c8dt04960b

upstream raw materials:

1,10-Phenanthroline

1,10-phenanthroline hydrochloride

sodium tetrachloroaurate(III)