{Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*SbF₆^(1-)={Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}SbF₆

Base Information

• Chemical Name: {Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*SbF₆^(1-)={Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}SbF₆
• CAS No.: 86802-75-7
• Molecular Formula: C₅₁H₄₉P₄Pt₂*F₆Sb
• Molecular Weight: 1411.75
• Mol file: 86802-75-7.mol

Synonyms:{Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*SbF₆^(1-)={Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}SbF₆

Chemical Property of {Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*SbF₆^(1-)={Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}SbF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*SbF₆^(1-)={Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}SbF₆

There total 1 articles about {Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}⁽¹⁺⁾*SbF₆^(1-)={Pt₂H₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)2}SbF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

sodium tetrahydroborate (16940-66-2) + [((C6H5)2PCH2P(C6H5)2)2Pt2Cl2CH3](1+)*SbF6(1-)=[((C6H5)2PCH2P(C6H5)2)2Pt2Cl2CH3]SbF6 (86802-73-5) → {Pt2H2(CH3)((C6H5)2PCH2P(C6H5)2)2}(1+)*SbF6(1-)={Pt2H2(CH3)((C6H5)2PCH2P(C6H5)2)2}SbF6 (86802-75-7)

Guidance literature:

In methanol; dichloromethane; soln. of NaBH4 in MeOH added to soln. of Pt complex in CH2Cl2, stirred under N2 in dark at room temp. for 30 min; evapd., dried in vac., extd. with CH2Cl2, concd., pptd. by addn. of Et2O; elem. anal.;

Reference yield: 96.0%

{Pt2H2(CH3)((C6H5)2PCH2P(C6H5)2)2}(1+)*SbF6(1-)={Pt2H2(CH3)((C6H5)2PCH2P(C6H5)2)2}SbF6 (86802-75-7) + bis-diphenylphosphinomethane (2071-20-7) → Pt2(CH3)((C6H5)2PCH2P(C6H5)2)3(1+)*SbF6(1-)=(Pt2(CH3)((C6H5)2PCH2P(C6H5)2)3)SbF6 (84190-23-8)

Guidance literature:

In dichloromethane; byproducts: H2; a soln. of Pt-complex and dppm in CH2Cl2 was stirred under N2 for 18 h at room temp.; soln. was concd. by evapn., product was crystd. out by addn. of Et2O; elem. anal., H2 detd. by GC;

DOI:10.1021/om00083a009

Reference yield: 90.0%

{Pt2H2(CH3)((C6H5)2PCH2P(C6H5)2)2}(1+)*SbF6(1-)={Pt2H2(CH3)((C6H5)2PCH2P(C6H5)2)2}SbF6 (86802-75-7) + acetonitrile (75-05-8,26809-02-9) + hexafluoro-2-butyne (692-50-2) → [((C6H5)2PCH2P(C6H5)2)2Pt2H(CF3CCCF3)(NCCH3)](1+)*SbF6(1-)=[((C6H5)2PCH2P(C6H5)2)2Pt2H(CF3CCCF3)(NCCH3)]SbF6 (86802-78-0) + [((C6H5)2PCH2P(C6H5)2)2Pt2CH3(CF3CCCF3)(NCCH3)](1+)*SbF6(1-)=[((C6H5)2PCH2P(C6H5)2)2Pt2CH3(CF3CCCF3)(NCCH3)]SbF6 (86851-43-6)

Guidance literature:

In acetonitrile; byproducts: CH4, H2; CF3CCCF3 condensed into tube containing suspn. of Pt complex in MeCN, sealed, allowed to stand at room temp. in dark for 3 d; pptd. by addn. of pentane;

upstream raw materials:

sodium tetrahydroborate

[((C₆H₅)2PCH₂P(C₆H₅)2)2Pt₂Cl₂CH₃]⁽¹⁺⁾*SbF₆^(1-)=[((C₆H₅)2PCH₂P(C₆H₅)2)2Pt₂Cl₂CH₃]SbF₆

Downstream raw materials:

Pt₂(CH₃)(P(C₆H₅)3)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*SbF₆^(1-)=(Pt₂(CH₃)(P(C₆H₅)3)((C₆H₅)2PCH₂P(C₆H₅)2)2)SbF₆

[Pt₂(H)(C₅H₅N)((C₆H₅)2PCH₂P(C₆H₅)2)2]⁽¹⁺⁾

Pt₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)3⁽¹⁺⁾*SbF₆^(1-)=(Pt₂(CH₃)((C₆H₅)2PCH₂P(C₆H₅)2)3)SbF₆

Pt₂(CH₃)(P(CH₃)2C₆H₅)((C₆H₅)2PCH₂P(C₆H₅)2)2⁽¹⁺⁾*SbF₆^(1-)=(Pt₂(CH₃)(P(CH₃)2C₆H₅)((C₆H₅)2PCH₂P(C₆H₅)2)2)SbF₆