methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside

Base Information

• Chemical Name: methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside
• CAS No.: 3650-62-2
• Molecular Formula: C₁₄H₁₅NO₆
• Molecular Weight: 293.276
• Mol file: 3650-62-2.mol

Synonyms:methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside

Chemical Property of methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside

There total 1 articles about methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside (3650-62-2)

Guidance literature:

Methyl-4,6-O-benzyliden-3-deoxy-3-nitro-β-D-galactopyranosid, Natriumacetat, Acetanhydrid;

DOI:10.1139/v65-240

Reference yield: 94.0%

methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside (3650-62-2) → methyl 2,3-anhydro-4,6-O-benzylidene-3-C-nitro-β-D-gulopyranoside (34379-91-4)

Guidance literature:

With tert.-butylhydroperoxide; sodium hydroxide; cetyltributylphosphonium bromide; In benzene; for 1.5h; Ambient temperature;

DOI:10.1016/0008-6215(89)85067-0

Reference yield: 91.0%

methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-β-D-threo-hex-2-enopyranoside (3650-62-2) + p-toluenesulfinic acid sodium salt dihydrate (824-79-3,7257-26-3) → methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-2-C-p-tolylsulfonyl-β-D-galactopyranoside (111614-24-5)

Guidance literature:

cetyltributylphosphonium bromide; In water; acetic acid; benzene; for 6h; Ambient temperature;

DOI:10.1016/0008-6215(87)80250-1

Downstream raw materials:

methyl 4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-2-C-p-tolylsulfonyl-β-D-galactopyranoside

methyl 2,3-anhydro-4,6-O-benzylidene-3-C-nitro-β-D-gulopyranoside

methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-methyl-3-nitro-β-D-galactopyranoside

methyl 4,6-O-benzylidene-2,3-dideoxy-3-nitro-2-C-vinyl-β-D-galactopyranoside