trans-[PtH(Ph)(P-t-Bu₂Me)2]

Base Information

Chemical Name:trans-[PtH(Ph)(P-t-Bu₂Me)2]
CAS No.:90064-99-6
Molecular Formula:C₂₄H₄₈P₂Pt
Molecular Weight:593.673
Hs Code.:

Synonyms:trans-[PtH(Ph)(P-t-Bu₂Me)2]

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Chemical Property of trans-[PtH(Ph)(P-t-Bu₂Me)2]

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Technology Process of trans-[PtH(Ph)(P-t-Bu₂Me)2]

There total 3 articles about trans-[PtH(Ph)(P-t-Bu₂Me)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 76316-26-2
trans-Pt(Cl)Ph(P-t-Bu₂Me)2

: 90064-99-6
trans-[PtH(Ph)(P-t-Bu₂Me)2]

Guidance literature:: With methanol; sodium methylate; In methanol; under N2, suspn. of Pt-complex in dry MeOH was treated with 2.8 equiv of NaOCH3, heated under reflux with stirring for 2 h; solvent evapd. under reduced pressure, extd. with n-hexane and water, n-hexane layer sepd., filtered through activated charcoal, dried (Na2SO4), solvent evapd., recrystd. from CH2Cl2-MeOH; elem. anal.;

Reference yield:

: 76124-94-2
trans-[PtOH(Ph)(P-t-Bu₂Me)2]

: 90064-99-6
trans-[PtH(Ph)(P-t-Bu₂Me)2]

Guidance literature:: With methanol; In methanol; under N2, suspn. of Pt-complex in dry MeOH was stirred for 3 h at room temp.; filtered under N2, dried in vac.; identified by (1)H NMR spectra;

Reference yield:

: 16940-66-2
sodium tetrahydroborate

: 76316-26-2
trans-Pt(Cl)Ph(P-t-Bu₂Me)2

: 90064-99-6
trans-[PtH(Ph)(P-t-Bu₂Me)2]

Guidance literature:: In ethanol; under N2, 5.3 equiv of NaBH4 was added to soln. of Pt-complex in abs. EtOH, stirred at room temp. for 2 h; solvent evapd. under reduced pressure, extd. with n-hexane and water, n-hexane layer sepd., filtered through activated charcoal, dried (Na2SO4), evapd.; elem. anal.;