Technology Process of C45H84O6Si2
There total 17 articles about C45H84O6Si2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium acetate; toluene-4-sulfonic acid hydrazide;
In
1,2-dimethoxyethane; water;
for 4h;
Reflux;
DOI:10.1021/ol1028699
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 3 h / 0 - 20 °C
1.2: (+/-)-CSA / 6 h / 0 - 20 °C
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C
2.2: 1.33 h / -78 - -20 °C
3.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
3.2: 2 h
4.1: 4-Bromobenzoic acid; di-isopropyl azodicarboxylate; triphenylphosphine / diethyl ether / 16 h / 20 °C
4.2: 4 h / 20 °C
5.1: 1H-imidazole / dichloromethane / 16 h / 20 °C
6.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -78 - -50 °C
6.2: 1.5 h
7.1: sodium acetate; toluene-4-sulfonic acid hydrazide / 1,2-dimethoxyethane; water / 4 h / Reflux
With
1H-imidazole; n-butyllithium; oxalyl dichloride; 4-Bromobenzoic acid; di-isopropyl azodicarboxylate; sodium acetate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; toluene-4-sulfonic acid hydrazide; triphenylphosphine;
In
tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; hexane; dichloromethane; water;
DOI:10.1021/ol1028699
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 1 h / -78 °C
1.2: 1.33 h / -78 - -20 °C
2.1: n-butyllithium / tetrahydrofuran; hexane / 1 h / -78 °C
2.2: 2 h
3.1: 4-Bromobenzoic acid; di-isopropyl azodicarboxylate; triphenylphosphine / diethyl ether / 16 h / 20 °C
3.2: 4 h / 20 °C
4.1: 1H-imidazole / dichloromethane / 16 h / 20 °C
5.1: n-butyllithium / tetrahydrofuran; hexane / 0.17 h / -78 - -50 °C
5.2: 1.5 h
6.1: sodium acetate; toluene-4-sulfonic acid hydrazide / 1,2-dimethoxyethane; water / 4 h / Reflux
With
1H-imidazole; n-butyllithium; oxalyl dichloride; 4-Bromobenzoic acid; di-isopropyl azodicarboxylate; sodium acetate; dimethyl sulfoxide; toluene-4-sulfonic acid hydrazide; triphenylphosphine;
In
tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; hexane; dichloromethane; water;
DOI:10.1021/ol1028699
