CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

Base Information

Chemical Name:CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2
CAS No.:503859-68-5
Molecular Formula:C₃₅H₂₉FeOPS
Molecular Weight:584.501
Hs Code.:

CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>SO(C<sub>5</sub>H<sub>3</sub>)Fe(C<sub>5</sub>H<sub>5</sub>)(C<sub>6</sub>H<sub>4</sub>)P(C<sub>6</sub>H<sub>5</sub>)2

Synonyms:CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

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Chemical Property of CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

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Technology Process of CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

There total 1 articles about CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 130225-27-3,164297-25-0,238753-24-7
(S_S)-ferrocenyl p-tolylsulfoxide

: 106865-17-2
(2-bromophenyl)-di(o-tolyl)phosphine borane

: 503859-68-5
CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

Guidance literature:: With lithium diisopropylamide; ZnBr₂; Pd(dibenzylideneacetonato)2; In tetrahydrofuran; Li diisopropylamide in THF added (-78 °C) to soln. of Fe-complex;stirred (30 min); ZnBr2 in THF added; warmed to room temp.; after 1 h s olvent evapd. in vac., residue dissolved in THF; soln. of Pd(dba)2 and tris-o-furylphosphine added; stirred..; quenched with water, aq. phase extd. with (C2H5)2O, combined org. phaseswashed with brine and dried over MgSO4; solvent removed under reduced p ressure; purified by column chromy. (silica gel, pentane/(C2H5)2O 1:2);
DOI:10.1039/b207399d

Reference yield: 81.0%

: 503859-68-5
CH₃C₆H₄SO(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 503859-71-0,1044281-78-8
(C₆H₅)2P(C₅H₃)Fe(C₅H₅)(C₆H₄)P(C₆H₅)2

Guidance literature:: With LiC(CH₃)3; In tetrahydrofuran; LiC(CH3)3 in THF added slowly to soln. of (CH3C6H4)SO(C5H3)Fe(C5H5)(C6H4)P(C6H5)2 at -78 °C; stirred for 5 min; ClP(C6H5)2 added dropwise; mixt. stirred for 5 min at -78°C and for 30 min at room temp.; quenched with satd. aq. NH4Cl, aq. phase extd. with (C2H5)2O, combined org. phases washed with brine and dried over MgSO4; solvent removed underreduced pressure; purified by column chromy. (silica gel, pentane/(C2H5 )2O 50:1);
DOI:10.1039/b207399d