methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

Base Information

Chemical Name:methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate
CAS No.:1401606-55-0
Molecular Formula:C₁₃H₁₅F₃O₈S
Molecular Weight:388.319
Hs Code.:

Synonyms:methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

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Chemical Property of methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

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Technology Process of methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

There total 2 articles about methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: ethoxymethoxyl chloride

: 19722-76-0
methyl-2,6-dihydroxy-4-methoxybenzoate

: 1401606-55-0
methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

Guidance literature:: ethoxymethoxyl chloride; methyl-2,6-dihydroxy-4-methoxybenzoate; With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 0 - 20 ℃;

With dmap; N,N-phenylbistrifluoromethane-sulfonimide; triethylamine; In dichloromethane; at 20 ℃; for 18h;
DOI:10.1021/ol302498v

Reference yield:

: 83-30-7
acide 2,4,6-trihydroxybenzoique

: 1401606-55-0
methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: potassium carbonate / acetone / 18 h / 20 °C

2.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0 - 20 °C

2.2: 18 h / 20 °C

With potassium carbonate; N-ethyl-N,N-diisopropylamine; In dichloromethane; acetone;
DOI:10.1021/ol302498v

Reference yield: 87.0%

: 1401606-55-0
methyl 2-(ethoxymethoxy)-4-methoxy-6-(((trifluoromethyl)sulfonyl)oxy)benzoate

: tert-butyl(((4R,5S)-2,2-dimethyl-5-(prop-2-yn-1-yl)-1,3-dioxolan-4-yl)methoxy)dimethylsilane

: 1401606-56-1
methyl 2-(3-((4S,5R)-5-(((tert-butyldimethylsilyl)oxy)methyl)-2,2-dimethyl-1,3-dioxolan-4-yl)prop-1-yn-1-yl)-6-(ethoxymethoxy)-4-methoxybenzoate

Guidance literature:: With copper(l) iodide; palladium diacetate; triethylamine; triphenylphosphine; In N,N-dimethyl-formamide; at 20 ℃; for 18h; Inert atmosphere;
DOI:10.1021/ol302498v