C₅₈H₈₂O₉SSi

Base Information

Chemical Name:C₅₈H₈₂O₉SSi
CAS No.:889109-14-2
Molecular Formula:C₅₈H₈₂O₉SSi
Molecular Weight:983.435
Hs Code.:

C<sub>58</sub>H<sub>82</sub>O<sub>9</sub>SSi

Synonyms:C₅₈H₈₂O₉SSi

Suppliers and Price of C₅₈H₈₂O₉SSi

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₅₈H₈₂O₉SSi

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₅₈H₈₂O₉SSi

There total 14 articles about C₅₈H₈₂O₉SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 858346-21-1
(2R,3S,4aR,6S,7R,8aS)-7-Benzyloxy-6-(2-benzyloxy-ethyl)-2,6,8a-trimethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-ol

: 889109-13-1
tert-Butyl-[(2S,3R,4aS,8aS,9aR,10aR)-2-((R)-3-chloro-2-methyl-3-phenylsulfanyl-propyl)-4a,5-dimethyl-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-3-yloxy]-dimethyl-silane

: 889109-14-2
C₅₈H₈₂O₉SSi

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; 4 A molecular sieve; silver trifluoromethanesulfonate; In dichloromethane; at -45 ℃; for 2h;
DOI:10.1021/jo0603025

Reference yield:

: 858346-53-9
(2R,4aR,6R,7S,8aR,9aS,10aS)-6-(tert-Butyl-dimethyl-silanyloxy)-7-[(R)-3-(tert-butyl-dimethyl-silanyloxy)-2-methyl-propyl]-10a-methyl-2-phenyl-octahydro-1,3,8,10-tetraoxa-anthracene

: 889109-14-2
C₅₈H₈₂O₉SSi

Guidance literature:: Multi-step reaction with 14 steps

1.1: H₂ / Pd(OH)2/C / ethyl acetate / 4 h

2.1: 77 percent / KH / tetrahydrofuran / 2 h / 35 °C

3.1: 100 percent / HMDS; TMSI / CH₂Cl₂ / 1 h / 0 °C

4.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

5.1: tetrahydrofuran / 0.5 h / 0 °C

6.1: (COCl)2; DMSO; Et₃N / CH₂Cl₂ / -78 - 20 °C

7.1: NaHMDS / tetrahydrofuran / 0 °C

7.2: 298 mg / tetrahydrofuran / 1 h / 20 °C

8.1: 84 percent / DDQ; aq. NaHCO₃ / CH₂Cl₂ / 1.5 h / 45 °C

9.1: KH / tetrahydrofuran / 1 h / 0 °C

10.1: 176 mg / (PCy₃)2Cl₂Ru=CHPh / CH₂Cl₂ / 20 h / 20 °C

11.1: 95 percent / CSA / methanol; CH₂Cl₂ / 2.5 h / 0 °C

12.1: 95 percent / Bu₃P / dimethylformamide / 4 h / 20 °C

13.1: NCS / CCl₄; CH₂Cl₂ / 0.5 h / 20 °C

14.1: 30 percent / DTBMP; AgOTf; 4 Angstroem molecular sieves / CH₂Cl₂ / 2 h / -45 °C

With N-chloro-succinimide; Grubbs catalyst first generation; 2,6-di-tert-butyl-4-methylpyridine; oxalyl dichloride; trimethylsilyl iodide; tributylphosphine; 4 A molecular sieve; camphor-10-sulfonic acid; hydrogen; silver trifluoromethanesulfonate; sodium hexamethyldisilazane; potassium hydride; sodium hydrogencarbonate; dimethyl sulfoxide; triethylamine; 1,1,1,3,3,3-hexamethyl-disilazane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium dihydroxide; In tetrahydrofuran; methanol; tetrachloromethane; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; 4.1: Swern oxidation / 5.1: Grignard reaction / 6.1: Swern oxidation / 7.2: Wittig reaction;
DOI:10.1021/jo0603025

Reference yield:

: 889109-11-9
(R)-3-[(2S,3R,4aS,8aS,9aR,10aR)-3-(tert-Butyl-dimethyl-silanyloxy)-4a,5-dimethyl-3,4,4a,7,8a,9,9a,10a-octahydro-2H-1,8,10-trioxa-anthracen-2-yl]-2-methyl-propan-1-ol

: 889109-14-2
C₅₈H₈₂O₉SSi

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / Bu₃P / dimethylformamide / 4 h / 20 °C

2: NCS / CCl₄; CH₂Cl₂ / 0.5 h / 20 °C

3: 30 percent / DTBMP; AgOTf; 4 Angstroem molecular sieves / CH₂Cl₂ / 2 h / -45 °C

With N-chloro-succinimide; 2,6-di-tert-butyl-4-methylpyridine; tributylphosphine; 4 A molecular sieve; silver trifluoromethanesulfonate; In tetrachloromethane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo0603025