Technology Process of Tricyclo(5.5.0.02,8)dodeca-3,5-diene
There total 4 articles about Tricyclo(5.5.0.02,8)dodeca-3,5-diene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
potassium tert-butylate;
In
tetrahydrofuran;
for 3h;
Ambient temperature;
DOI:10.1021/ja00224a037
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 99 percent / hydrogen / 5percent palladium on carbon / methanol / 1.3 h
2: 78 percent / titanium trichloride tris(tetrahydrofuran) complex, potassium / 1,2-dimethoxy-ethane / 25.5 h / Heating
3: 80 percent / pyridinium bromide perbromide / acetic acid; CCl4 / 2.3 h / Ambient temperature
4: 83 percent / potassium tert-butoxide / tetrahydrofuran / 3 h / Ambient temperature
With
titanium trichloride tris(tetrahydrofuran); potassium tert-butylate; hydrogen; pyridinium hydrobromide perbromide; potassium;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; tetrachloromethane; 1,2-dimethoxyethane; acetic acid;
DOI:10.1021/ja00224a037
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 80 percent / pyridinium bromide perbromide / acetic acid; CCl4 / 2.3 h / Ambient temperature
2: 83 percent / potassium tert-butoxide / tetrahydrofuran / 3 h / Ambient temperature
With
potassium tert-butylate; pyridinium hydrobromide perbromide;
In
tetrahydrofuran; tetrachloromethane; acetic acid;
DOI:10.1021/ja00224a037
