9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

Base Information

Chemical Name:9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide
CAS No.:303089-30-7
Molecular Formula:C₄₁H₃₉NO₂Si
Molecular Weight:605.852
Hs Code.:

Synonyms:9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

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Technology Process of 9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

There total 4 articles about 9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 165261-51-8
9-bromo-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

: 1066-54-2
trimethylsilylacetylene

: 303089-30-7
9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

Guidance literature:: With copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; diisopropylamine; In dichloromethane; at 60 ℃; for 36h; Schlenk technique; Inert atmosphere;
DOI:10.1039/C8DT02496K

Reference yield:

: 21860-03-7
2,5-di-tert-butylaniline

: 303089-30-7
9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

Guidance literature:: Multi-step reaction with 3 steps

1: zinc diacetate; 1H-imidazole / water / 22 h / 190 °C / Schlenk technique; Inert atmosphere

2: N-Bromosuccinimide / N,N-dimethyl-formamide / 48 h / 20 - 40 °C / Schlenk technique; Inert atmosphere

3: diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) iodide / dichloromethane / 36 h / 60 °C / Schlenk technique; Inert atmosphere

With 1H-imidazole; N-Bromosuccinimide; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; zinc diacetate; diisopropylamine; In dichloromethane; water; N,N-dimethyl-formamide; 3: |Sonogashira Cross-Coupling;
DOI:10.1039/C8DT02496K

Reference yield:

: 165261-25-6
N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

: 303089-30-7
9-(trimethylsilylethynyl)-N-(2,5-di-tert-butylphenyl)-perylene-3,4-dicarboxylic imide

Guidance literature:: Multi-step reaction with 2 steps

1: N-Bromosuccinimide / N,N-dimethyl-formamide / 48 h / 20 - 40 °C / Schlenk technique; Inert atmosphere

2: diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; copper(l) iodide / dichloromethane / 36 h / 60 °C / Schlenk technique; Inert atmosphere

With N-Bromosuccinimide; copper(l) iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; diisopropylamine; In dichloromethane; N,N-dimethyl-formamide; 2: |Sonogashira Cross-Coupling;
DOI:10.1039/C8DT02496K