tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate

Base Information

• Chemical Name: tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate
• CAS No.: 77451-12-8
• Molecular Formula: C₄H₁₂N*C₄₂H₄₂O₆P₃S₆Zn
• Molecular Weight: 1067.65
• Mol file: 77451-12-8.mol

Synonyms:tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate

Chemical Property of tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate

There total 3 articles about tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

(Zn(S2P(OC6H4Me-p)2)2) (74895-05-9) + (NMe4)(S2P(OC6H4Me-p)2) → tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate (77451-12-8)

Guidance literature:

In isopropyl alcohol; to soln. (Zn(S2P(OC6H4Me-p)2)2) in propan-2-ol added slowly with stirring and gentle heating suspn. (NMe4)(S2P(OC6H4Me-p)2) in propan-2-ol; soln. cooled, crystals filtered off and recrystd. from toluene; elem. anal.;

DOI:10.1039/DT9830000627

Reference yield: 25.0%

tetramethyl ammonium stearate (55489-71-9) + (Zn(S2P(OC6H4Me-p)2)2) (74895-05-9) → tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate (77451-12-8) + zinc stearate (557-05-1) + (NMe4)(S2P(OC6H4Me-p)2)

Guidance literature:

In isopropyl alcohol; soln. (NMe4)(OCOC17H35) in propan-2-ol added slowly with stirring to (Zn(S2P(OC6H4Me-p)2)2) in propan-2-ol; ppt. (zinc stearate) filtered off, soln. allowed to stand at room temp.for 24 h, (NMe4)(Zn(S2P(OC6H4Me-p)2)3) filtered off, mother-liquor evapd. in vacuo - (NMe4)(S2P(OC6H4Me-p)2);

DOI:10.1039/DT9830000627

Reference yield:

O,O-di-p-tolyl hydrogen phosphorodithioate (14366-43-9) → tetramethylammonium bis(OO'-di-p-tolyl dithiophosphato-S) (OO'-di-p-tolyl dithiophosphato-SS')zincate (77451-12-8)

Guidance literature:

Multi-step reaction with 2 steps

1: water; toluene

2: isopropyl alcohol

In water; isopropyl alcohol; toluene;

DOI:10.1039/DT9830000627

upstream raw materials:

tetramethyl ammonium stearate

(Zn(S₂P(OC₆H₄Me-p)2)2)

O,O-di-p-tolyl hydrogen phosphorodithioate