4-iPr₃SiCCC₆H₄-1-CCC₆H₄-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₄-4-NO₂

Base Information

• Chemical Name: 4-iPr₃SiCCC₆H₄-1-CCC₆H₄-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₄-4-NO₂
• CAS No.: 1174823-45-0
• Molecular Formula: C₅₇H₅₇NO₆Si
• Molecular Weight: 880.168
• Mol file: 1174823-45-0.mol

Synonyms:4-iPr₃SiCCC₆H₄-1-CCC₆H₄-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₄-4-NO₂

Chemical Property of 4-iPr₃SiCCC₆H₄-1-CCC₆H₄-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₄-4-NO₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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Useful:

Technology Process of 4-iPr₃SiCCC₆H₄-1-CCC₆H₄-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₄-4-NO₂

There total 1 articles about 4-iPr₃SiCCC₆H₄-1-CCC₆H₄-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₂-2,5-(OEt)2-4-CCC₆H₄-4-NO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

C25H29ISi (1173821-50-5) + C32H29NO6 (1174823-38-1) → 4-iPr3SiCCC6H4-1-CCC6H4-4-CCC6H2-2,5-(OEt)2-4-CCC6H2-2,5-(OEt)2-4-CCC6H4-4-NO2 (1174823-45-0)

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In dichloromethane; at 20 ℃; for 48h; Inert atmosphere;

DOI:10.1021/ja902793z

Reference yield: 47.0%

cis-dichlorodi[bis(diphenylphosphino)methane]ruthenium(II) + 4-iPr3SiCCC6H4-1-CCC6H4-4-CCC6H2-2,5-(OEt)2-4-CCC6H2-2,5-(OEt)2-4-CCC6H4-4-NO2 (1174823-45-0) → trans-[Ru(4,4',4'',4''',4''''-CCC6H4CCC6H4CCC6H2[2,5-(OEt)2]CCC6H2[2,5-(OEt)2]CCC6H4NO2)Cl(dppm)2]

Guidance literature:

With NaPF₆; triethylamine; In dichloromethane; (N)2 Ru complex and NaPF6 were added to soln. ligand in CH2Cl2, stirred at room temp. overnight, Et3N was added, stirred at room temp. for 6 h; react. mixt. was passed through short alumina pad (CH2Cl2/petrol/NEt3, 10:10:1), solvent was evapd.;

DOI:10.1021/ja902793z

upstream raw materials:

C₂₅H₂₉ISi

C₃₂H₂₉NO₆