Rhodium, [[2-[[bis[3-(trifluoromethyl)phenyl]phosphino-.kappa.P]methyl]-2-methyl-1,3-propanediyl]bis[bis[3-(trifluoromethyl)phenyl]phosphine-..kappa.P]]carbonylchloro-, (TB-5-12)-

Base Information

Chemical Name:Rhodium, [[2-[[bis[3-(trifluoromethyl)phenyl]phosphino-.kappa.P]methyl]-2-methyl-1,3-propanediyl]bis[bis[3-(trifluoromethyl)phenyl]phosphine-..kappa.P]]carbonylchloro-, (TB-5-12)-
CAS No.:204906-18-3
Molecular Formula:C48H33ClF18OP3Rh-
Molecular Weight:1199.04
Hs Code.:

Rhodium, [[2-[[bis[3-(trifluoromethyl)phenyl]phosphino-.kappa.P]methyl]-2-methyl-1,3-propanediyl]bis[bis[3-(trifluoromethyl)phenyl]phosphine-..kappa.P]]carbonylchloro-, (TB-5-12)-

Synonyms:

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Chemical Property of Rhodium, [[2-[[bis[3-(trifluoromethyl)phenyl]phosphino-.kappa.P]methyl]-2-methyl-1,3-propanediyl]bis[bis[3-(trifluoromethyl)phenyl]phosphine-..kappa.P]]carbonylchloro-, (TB-5-12)-

Chemical Property:

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Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Rhodium, [[2-[[bis[3-(trifluoromethyl)phenyl]phosphino-.kappa.P]methyl]-2-methyl-1,3-propanediyl]bis[bis[3-(trifluoromethyl)phenyl]phosphine-..kappa.P]]carbonylchloro-, (TB-5-12)-

There total 2 articles about Rhodium, [[2-[[bis[3-(trifluoromethyl)phenyl]phosphino-.kappa.P]methyl]-2-methyl-1,3-propanediyl]bis[bis[3-(trifluoromethyl)phenyl]phosphine-..kappa.P]]carbonylchloro-, (TB-5-12)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: di(rhodium)tetracarbonyl dichloride

: 204906-16-1
CH₃C(CH₂P(C₆H₄CF₃)2)3

: 204906-18-3
RhCl(CO)(CH₃C(CH₂P(C₆H₄CF₃)2)3)

Guidance literature:: In hexane; toluene; byproducts: CO; Ar-atmosphere; dropwise addn. of Rh-complex (in PhMe) to slight excess of ligand (in hexane) at room temp. (pptn.); hexane addn., collection (filtration), washing (hexane), drying (vac.); elem. anal.;
DOI:10.1016/s0020-1693(97)06115-x

Reference yield:

: 15318-33-9,16353-77-8,13938-94-8
chlorocarbonylbis(triphenylphosphine)rhodium(I)

: 204906-16-1
CH₃C(CH₂P(C₆H₄CF₃)2)3

: 204906-18-3
RhCl(CO)(CH₃C(CH₂P(C₆H₄CF₃)2)3)

Guidance literature:: In not given; Ar-atmosphere;
DOI:10.1016/s0020-1693(97)06115-x

Reference yield:

: 204906-18-3
[RhCl(CO)(CH₃C(CH₂P(m-CF₃C₆H₄)2)3)]

: 378784-00-0,7440-16-6
rhodium

Guidance literature:: In solid; thermal decomposition in dynamic N2 atm., heating at 57-700°C, the intermediate products formed at about 103 and 360°C; Kinetics;
DOI:10.1016/S0040-6031(00)00717-6