3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide

Base Information

• Chemical Name: 3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide
• CAS No.: 861100-48-3
• Molecular Formula: C₁₉H₂₂O₅
• Molecular Weight: 330.381
• Mol file: 861100-48-3.mol

Synonyms:3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide

Chemical Property of 3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide

There total 2 articles about 3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

methyl 3,5-di-O-benzyl-2-deoxy-β-D-erythro-pentofuranoside (6160-55-0) → 3,5-di-O-benzyl-2-deoxy-β-D-erythropentofuranosyl hydroperoxide (861100-51-8) + 3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide (861100-48-3)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In 1,4-dioxane; at 20 ℃;

DOI:10.1016/j.tetasy.2005.04.009

Reference yield: 42.0%

methyl 3,5-di-O-benzyl-2-deoxy-α-D-erythro-pentofuranoside (6160-54-9) → 3,5-di-O-benzyl-2-deoxy-β-D-erythropentofuranosyl hydroperoxide (861100-51-8) + 3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide (861100-48-3)

Guidance literature:

With sulfuric acid; dihydrogen peroxide; In 1,4-dioxane; at 20 ℃;

DOI:10.1016/j.tetasy.2005.04.009

Reference yield: 29.0%

3,5-di-O-benzyl-2-deoxy-α-D-erythropentofuranosyl hydroperoxide (861100-48-3) + 3,4,6-tri-O-benzyl-D-galactal (80040-79-5) → 3,5-di-O-benzyl-2-deoxy-α-D-ribofuranosyl(3,4,6-tri-O-benzyl-2-deoxy-α-D-galactopyranosyl)peroxide

Guidance literature:

With (+)-10-camphorsulfonic acid; In dichloromethane; for 2h;

DOI:10.1055/s-2007-991090

upstream raw materials:

methyl 3,5-di-O-benzyl-2-deoxy-β-D-erythro-pentofuranoside

methyl 3,5-di-O-benzyl-2-deoxy-α-D-erythro-pentofuranoside