(5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien

Base Information

• Chemical Name: (5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien
• CAS No.: 106929-39-9
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.236
• Mol file: 106929-39-9.mol

Synonyms:(5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien

Chemical Property of (5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien

There total 1 articles about (5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

(1S,3S,6R)-(-)-4-Caren-3α-ol (4017-81-6) → (5S)-(-)-5β-(1-Hydroxy-1-methylethyl)-1-methyl-1,3-cyclohexadien (5208-31-1) + (5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien (106929-39-9)

Guidance literature:

With phosphoric acid; dihydrogen peroxide; In dichloromethane; for 3h; Ambient temperature;

Reference yield: 95.0%

(5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien (106929-39-9) → (5S)-(-)-5β-(1-Hydroxy-1-methylethyl)-1-methyl-1,3-cyclohexadien (5208-31-1)

Guidance literature:

With sodium tetrahydroborate; In methanol; for 0.166667h;

Reference yield: 65.0%

4-Phenyl-1,2,4-triazolidine-3,5-dione (4233-33-4) + (5S)-(-)-5β-(1-Hydroperoxy-1-methylethyl)-1-methyl-1,3-cyclohexadien (106929-39-9) → (1S,4S,8S)-(-)-8-(1-Hydroperoxy-1-methylethyl)-1-methyl-N-phenyl-2,3-diazabicyclo<2.2.2>oct-5-en-2,3-dicarboximid (106929-40-2)

Guidance literature:

In dichloromethane; for 0.333333h; Ambient temperature;

upstream raw materials:

(1S,3S,6R)-(-)-4-Caren-3α-ol

Downstream raw materials:

(1S,4S,8S)-(-)-8-(1-Hydroperoxy-1-methylethyl)-1-methyl-N-phenyl-2,3-diazabicyclo<2.2.2>oct-5-en-2,3-dicarboximid

(5S)-(-)-5β-(1-Hydroxy-1-methylethyl)-1-methyl-1,3-cyclohexadien

(1S,2S,6S)-2α-Acetoxy-6β-(1-hydroxy-1-methylethyl)-4-methyl-3-cyclohexen-1β-ol