(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

Base Information

Chemical Name:(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one
CAS No.:117361-41-8
Molecular Formula:C₁₄H₂₂OSi
Molecular Weight:234.414
Hs Code.:

Synonyms:(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

Suppliers and Price of (E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

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Technology Process of (E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

There total 5 articles about (E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 117361-33-8
(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-ol

: 117361-41-8
(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

Guidance literature:: With barium permanganate; In dichloromethane; for 12h; Ambient temperature;
DOI:10.1002/hlca.19880710120

Reference yield:

: 41309-43-7
(2-bromovinyl)trimethylsilane

: 117361-41-8
(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) Mg, I₂ / 1.) THF, 2.) THF, -40 deg C

2: 80 percent / BaMnO₄ / CH₂Cl₂ / 12 h / Ambient temperature

With barium permanganate; iodine; magnesium; In dichloromethane;
DOI:10.1002/hlca.19880710120

Reference yield:

: 6-[1-Methoxy-meth-(Z)-ylidene]-4,4-dimethyl-cyclohex-2-enone

: 117361-41-8
(E)-1-(5',5'-dimethyl-1',3'-cyclohexadienyl)-3-(trimethylsilyl)-2-propen-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: 0.064 g / CeCl_3.7H₂O, NaBH₄ / methanol / 0.08 h / 5 °C

2: 1.) Mg, I₂ / 1.) THF, 2.) THF, -40 deg C

3: 80 percent / BaMnO₄ / CH₂Cl₂ / 12 h / Ambient temperature

With sodium tetrahydroborate; cerium(III) chloride; barium permanganate; iodine; magnesium; In methanol; dichloromethane;
DOI:10.1002/hlca.19880710120