(pTol-DPR)2*Ni

Base Information

Chemical Name:(pTol-DPR)2*Ni
CAS No.:847267-71-4
Molecular Formula:C₃₂H₂₆N₄Ni
Molecular Weight:525.275
Hs Code.:

Synonyms:(pTol-DPR)2*Ni

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Chemical Property of (pTol-DPR)2*Ni

Chemical Property:

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Technology Process of (pTol-DPR)2*Ni

There total 2 articles about (pTol-DPR)2*Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: nickel(II) chloride hexahydrate

: 147804-55-5
5-(4-methylphenyl)dipyrromethane

: 847267-71-4
(CH₃C₆H₄C(C₄H₃N)2)2Ni

Guidance literature:: With 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; triethyl amine; In tetrahydrofuran; methanol; to a soln. of meso-arylbisdipyrrin in THF was treated with DDQ at room temp., after 50 min (C2H5)3N was added, a methanolic soln. of NiCl2*6H2O was added, 45 min; reduced in vol., diluted with hexanes the soln. was filtered through a short plug of silica with diethyl ether-hexanes, crystd. from acetone-hexanes; elem. anal.;
DOI:10.1039/b412620c

Reference yield: 47.0%

: 373-02-4,14998-37-9,33025-09-1,94044-50-5,98268-31-6
nickel diacetate

: 147804-55-5
5-(4-methylphenyl)dipyrromethane

: 847267-71-4
(pTol-DPR)2*Ni

Guidance literature:: 5-(4-methylphenyl)dipyrromethane; With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In 1,2-dichloro-ethane; at 20 ℃; for 0.5h;

With triethylamine; In 1,2-dichloro-ethane; at 20 ℃; for 0.0833333h;

nickel diacetate; In 1,2-dichloro-ethane; for 2h; Reflux;
DOI:10.1016/j.poly.2015.10.020

Reference yield: 71.0%

: 847267-71-4
(CH₃C₆H₄C(C₄H₃N)2)2Ni

: 847267-73-6
(CH₃C₆H₄C(C₄H₃N)(C₄H₂N))2Ni

Guidance literature:: With 2,3-dichloro-5,6-dicyano-1,4-benzoquinone; In toluene; a soln. of complex in toluene was treated with DDQ and heated at reflux for 12 h; diluted with hexanes the soln. was filtered through a short plug of silica with CH2Cl2-hexanes, the solvents were slow removed;
DOI:10.1039/b412620c