2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline

Base Information

• Chemical Name: 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline
• CAS No.: 1330067-23-6
• Molecular Formula: C₂₂H₁₈N₄
• Molecular Weight: 338.412
• Mol file: 1330067-23-6.mol

Synonyms:2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline

Chemical Property of 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline

There total 2 articles about 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1,10-phenanthroline-5,6-dione (27318-90-7) + (4-isopropylbenzaldehyde) (122-03-2) → 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline (1330067-23-6)

Guidance literature:

With ammonium acetate; In acetic acid; for 4h; Reflux;

DOI:10.1007/s10895-010-0743-9

Reference yield:

1,10-Phenanthroline (66-71-7) → 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline (1330067-23-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sulfuric acid; nitric acid; sodium bromide / 2 h / Reflux

2: ammonium acetate; acetic acid

With sulfuric acid; ammonium acetate; nitric acid; acetic acid; sodium bromide;

DOI:10.1007/s10895-017-2151-x

Reference yield: 59.0%

potassium hexafluorophosphate (17084-13-8) + 2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline (1330067-23-6) + [(2-(3-fluorophenyl)-4-methylpyridine)2Ir( μ-Cl)]2 → C46H36F2IrN6(1+)*F6P(1-)

Guidance literature:

2-(4-isopropylphenyl)-1H-imidazo-[4,5-f ]-[1,10]-phenanthroline; [(2-(3-fluorophenyl)-4-methylpyridine)₂Ir( μ-Cl)]₂; In methanol; dichloromethane; for 12h; Reflux; Schlenk technique; Inert atmosphere;

potassium hexafluorophosphate; In methanol; dichloromethane; for 3h; Schlenk technique; Inert atmosphere;

DOI:10.1016/j.molstruc.2020.129415

upstream raw materials:

1,10-phenanthroline-5,6-dione

(4-isopropylbenzaldehyde)

1,10-Phenanthroline