N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

Base Information

Chemical Name:N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide
CAS No.:1094359-03-1
Molecular Formula:C₂₂H₃₇NO₄SSi
Molecular Weight:439.692
Hs Code.:

Synonyms:N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

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Technology Process of N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

There total 2 articles about N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 1094359-57-5
N-(2,2-bis(hydroxymethyl)pent-4-en-1-yl)-4-methylbenzenesulfonamide

: 85272-31-7
di-tert-butylsilyl bis(trifluoromethanesulfonate)

: 1094359-03-1
N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1021/ja806585m

Reference yield:

: 1094359-54-2
C₁₅H₃₁NO₂Si

: 98-59-9
p-toluenesulfonyl chloride

: 1094359-03-1
N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

Guidance literature:: With pyridine; In dichloromethane; at 20 ℃; for 24h;
DOI:10.1021/ja806585m

Reference yield: 78.0%

: 1094359-03-1
N-(5-allyl-2,2-di-tert-butyl-[1,3,2]dioxasilinan-5-ylmethyl)-4-methyl-benzenesulfonamide

: 1380538-93-1
(S)-8,8-di-tert-butyl-3-(iodomethyl)-2-tosyl-7,9-dioxa-2-aza-8-silaspiro[4.5]decane

Guidance literature:: With 2-iodo-propane; manganese(IV) oxide; copper(II) bis(trifluoromethanesulfonate); potassium carbonate; (4R,4'R,5S,5'S)-2,2'-(propane-2,2-diyl)bis(4,5-diphenyl-4,5-dihydrooxazole); In α,α,α-trifluorotoluene; at 105 ℃; for 11h; optical yield given as %ee; enantioselective reaction; Inert atmosphere; Molecular sieve;
DOI:10.1002/anie.201109044