Technology Process of C39H46O12
There total 14 articles about C39H46O12 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
phenyllithium;
In
tetrahydrofuran; dibutyl ether;
at -60 ℃;
for 0.166667h;
Inert atmosphere;
Cooling with acetone-dry ice;
- Guidance literature:
-
With
lithium borohydride;
In
tetrahydrofuran;
at -13 - 0 ℃;
for 13.25h;
ice/water/ammonium chloride bath;
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: hydrazine / Isopropyl acetate / 1 h / 20 °C
2.1: dmap / dichloromethane / 3 h / 20 °C
3.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 22 h / 20 °C
4.1: sodium tetrahydroborate / methanol; ethanol / 5 h / 0 °C
5.1: dmap / dichloromethane / 15 h / 20 °C
5.2: 0.08 h
6.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 20 °C
7.1: toluene-4-sulfonic acid / dichloromethane / 0.75 h / 20 °C
8.1: lithium borohydride / tetrahydrofuran / 13.25 h / -13 - 0 °C / ice/water/ammonium chloride bath
With
dmap; sodium tetrahydroborate; lithium borohydride; tetrapropylammonium perruthennate; tetrabutyl ammonium fluoride; 4-methylmorpholine N-oxide; hydrazine;
toluene-4-sulfonic acid;
In
tetrahydrofuran; methanol; ethanol; dichloromethane; Isopropyl acetate;