1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal

Base Information

• Chemical Name: 1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal
• CAS No.: 1203571-48-5
• Molecular Formula: C₂₃H₃₀O₂Si
• Molecular Weight: 367.568
• Mol file: 1203571-48-5.mol

Synonyms:1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal

Chemical Property of 1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of 1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal

There total 1 articles about 1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(E)-[1,1-2H2]-6-[(tert-butyldiphenylsilyl)oxy]-4-methylhex-4-en-1-ol (1203571-47-4) → 1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal (1203571-48-5)

Guidance literature:

With pyridinium chlorochromate; In dichloromethane; for 4h;

DOI:10.1002/chem.200901563

Reference yield: 71.0%

1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal (1203571-48-5) + isopropyltriphenylphosphonium iodide (24470-78-8) → (E)-[6-2H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane (1203571-49-6)

Guidance literature:

isopropyltriphenylphosphonium iodide; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.666667h; Inert atmosphere;

1-[D]-(E)-6-(tert-butyldiphenylsilyloxy)-4-methylhex-4-enal; In tetrahydrofuran; hexane; for 0.166667h; Inert atmosphere;

DOI:10.1002/chem.200901563

upstream raw materials:

(E)-[1,1-²H₂]-6-[(tert-butyldiphenylsilyl)oxy]-4-methylhex-4-en-1-ol

Downstream raw materials:

(E)-[6-²H]-tert-butyl[(3,7-dimethylocta-2,6-dien-1-yl)oxy]diphenylsilane