Cp(CO)2Re=C(Tol)CCCH₃

Base Information

Chemical Name:Cp(CO)2Re=C(Tol)CCCH₃
CAS No.:416872-47-4
Molecular Formula:C₁₈H₁₅O₂Re
Molecular Weight:449.523
Hs Code.:

Synonyms:Cp(CO)2Re=C(Tol)CCCH₃

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Chemical Property of Cp(CO)2Re=C(Tol)CCCH₃

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Technology Process of Cp(CO)2Re=C(Tol)CCCH₃

There total 1 articles about Cp(CO)2Re=C(Tol)CCCH₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

: 106865-70-7
{Cp(carbonyl)2rhenium(CTol)}{BCl₄}

: 4529-04-8
1-propynyl lithium

: 416872-47-4
Cp(CO)2Re=C(Tol)CCCH₃

Guidance literature:: With zinc dibromide; In tetrahydrofuran; BrZnCCCH3 prepared from LiCCCH3 and ZnBr2 in THF was added to soln. (Cp(CO)2ReCTol)BCl4 in THF at -75°C; after 10 min, cold react. mixt. was poured onto silicagel column, elutedwith hexane:Et2O (4:1), evapd., redissolved in hexane:CH2Cl2 (3:1), and evapd. slowly;
DOI:10.1021/ja011962o

Reference yield: 50.0%

: 416872-47-4
Cp(CO)2Re=C(Tol)CCCH₃

: [Cp(CO)2Re]2[η2,η2-(E)-TolCC(CH3)CC(CH3)CCTol]

Guidance literature:: In ⁽²⁾H₈-toluene; thermolysis in toluene-d8 at 100°C for 55 min; thin-layer chromy. (silica, hexane-Et2O (9:1), dissolved in CH2Cl2-hexane and evapd. slowly; Kinetics;
DOI:10.1021/ja011962o