phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

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Chemical Name:phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester
CAS No.:1054709-06-6
Molecular Formula:C₅₃H₈₇O₁₀PSi₄
Molecular Weight:1027.58
Hs Code.:

phosphoric acid mono-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-1-{3-[3-(<i>tert</i>-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2<i>H</i>-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(<i>tert</i>-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

Synonyms:phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

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Chemical Property of phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

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Technology Process of phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

There total 5 articles about phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 915700-44-6
phosphoric acid diallyl ester 3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl ester

: 1054709-06-6
phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; triethylamine; In tetrahydrofuran; at 50 ℃; for 1h;
DOI:10.1021/ol062111u

Reference yield:

: 915700-43-5
(5S,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-6-[(1E,7Z)-(3R,4R,6R)-6-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-8-iodo-3-methyl-3-triethylsilanyloxy-octa-1,7-dienyl]-5,6-dihydro-pyran-2-one

: 1054709-06-6
phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

Guidance literature:: Multi-step reaction with 4 steps

1: 96 percent / Pd(MeCN)2Cl₂ / dimethylformamide / 12 h / 0 °C

2: tetrazole / CH₂Cl₂ / 0.25 h / 20 °C

3: 99 mg / TBHP / CH₂Cl₂; methanol / 3.5 h / 0 °C

4: Et₃N; formic acid; Pd(PPh₃)4 / tetrahydrofuran / 1 h / 50 °C

With 1H-tetrazole; tert.-butylhydroperoxide; dichloro bis(acetonitrile) palladium(II); tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; 1: Stille coupling;
DOI:10.1021/ol062111u

Reference yield:

: (5S,6S,1'E,3'R,4'R,6'R,7'EZ)-5-(tert-butyl(dimethyl)silyloxy)-6-[6'-(tert-butyl(dimethyl)silyloxy)-8'-iodo-3'-methyl-3',4'-bis(triethylsilyloxy)-1',7'-octadienyl]-5,6-dihydro-2H-pyran-2-one

: 1054709-06-6
phosphoric acid mono-[3-(tert-butyl-dimethyl-silanyloxy)-1-{3-[3-(tert-butyl-dimethyl-silanyloxy)-6-oxo-3,6-dihydro-2H-pyran-2-yl]-1-methyl-1-triethylsilanyloxy-allyl}-10-(tert-butyl-diphenyl-silanyloxy)-deca-4,6,8-trienyl] ester

Guidance literature:: Multi-step reaction with 5 steps

1: 37 percent / HCl / tetrahydrofuran; acetonitrile / 4 h / -10 °C

2: 96 percent / Pd(MeCN)2Cl₂ / dimethylformamide / 12 h / 0 °C

3: tetrazole / CH₂Cl₂ / 0.25 h / 20 °C

4: 99 mg / TBHP / CH₂Cl₂; methanol / 3.5 h / 0 °C

5: Et₃N; formic acid; Pd(PPh₃)4 / tetrahydrofuran / 1 h / 50 °C

With 1H-tetrazole; hydrogenchloride; tert.-butylhydroperoxide; dichloro bis(acetonitrile) palladium(II); tetrakis(triphenylphosphine) palladium⁽⁰⁾; formic acid; triethylamine; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetonitrile; 2: Stille coupling;
DOI:10.1021/ol062111u