cis-[PdCl₂(CNtmbu)(triphenylphosphine)]

Base Information

• Chemical Name: cis-[PdCl₂(CNtmbu)(triphenylphosphine)]
• CAS No.: 1361117-31-8
• Molecular Formula: C₂₇H₃₂Cl₂NPPd
• Molecular Weight: 578.858
• Mol file: 1361117-31-8.mol

Synonyms:cis-[PdCl₂(CNtmbu)(triphenylphosphine)]

Chemical Property of cis-[PdCl₂(CNtmbu)(triphenylphosphine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis-[PdCl₂(CNtmbu)(triphenylphosphine)]

There total 3 articles about cis-[PdCl₂(CNtmbu)(triphenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

sym,trans-[PdCl2(PPh3)2] + 1,1,3,3-tetramethylbutane isonitrile (14542-93-9) → cis-[PdCl2(CNtmbu)(triphenylphosphine)] (1361117-31-8)

Guidance literature:

With diethyl ether; In dichloromethane; at 20 ℃;

DOI:10.1134/S1070363217110159

Reference yield: 87.0%

cis-[PdCl2(2-isocyano-2,4,4-trimethylpentane)2] (1361297-90-6,944150-84-9) + triphenylphosphine (603-35-0) → cis-[PdCl2(CNtmbu)(triphenylphosphine)] (1361117-31-8)

Guidance literature:

In diethyl ether; chloroform; soln. of PPh3 in Et2O added to soln. of Pd complex in CHCl3; refluxed for 1 h; filtered; filtrate evapd. to dryness under N2; successively washed with Et2O, i-Pr2O and Et2O; dried in vac. at 20-25°C; elem. anal.;

DOI:10.1021/om300020j

Reference yield:

1,1,3,3-tetramethylbutane isonitrile (14542-93-9) → cis-[PdCl2(CNtmbu)(triphenylphosphine)] (1361117-31-8)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform

2: chloroform; diethyl ether

In diethyl ether; chloroform;

DOI:10.1021/om300020j

upstream raw materials:

cis-[PdCl₂(2-isocyano-2,4,4-trimethylpentane)2]

triphenylphosphine

1,1,3,3-tetramethylbutane isonitrile