phenylphosphine-d2

Base Information

• Chemical Name: phenylphosphine-d2
• CAS No.: 18632-85-4
• Molecular Formula: C₆H₇P
• Molecular Weight: 112.079
• Mol file: 18632-85-4.mol

Synonyms:phenylphosphine-d2

Chemical Property of phenylphosphine-d2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenylphosphine-d2

There total 2 articles about phenylphosphine-d2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

phenylphosphine disodium salt → phenylphosphane (638-21-1) + deuterio-phenyl-phosphane (18632-86-5) + phenylphosphine-d2 (18632-85-4)

Guidance literature:

With tetradeuterioacetic acid; In diethyl ether; at -10 - 0 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.202110619

Reference yield:

phenylphosphane (638-21-1) → deuterio-phenyl-phosphane (18632-86-5) + phenylphosphine-d2 (18632-85-4)

Guidance literature:

With Et₃SiD; tris(pentafluorophenyl)borate; In benzene; at 100 ℃; for 8h; Kinetics; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1021/jacs.7b09175

Reference yield:

1,3-Dichloropropane (142-28-9) + phenylphosphine-d2 (18632-85-4) → C9H11(2)HClP

Guidance literature:

With sodium; In tetrahydrofuran; -78 deg C to r.t.;

DOI:10.1002/prac.19973390187

upstream raw materials:

phenylphosphane

Downstream raw materials:

[(N(CH₂CH₂NSi(CH₃)3)2C₂H₄NSi(CH₃)2CH₂⁽²⁾H)Zr(P⁽²⁾HC₆H₅)]