hex-5-mer-BME

Base Information

• Chemical Name: hex-5-mer-BME
• CAS No.: 1382734-92-0
• Molecular Formula: C₆₄H₇₀O₆
• Molecular Weight: 935.256
• Mol file: 1382734-92-0.mol

Synonyms:hex-5-mer-BME

Chemical Property of hex-5-mer-BME

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of hex-5-mer-BME

There total 7 articles about hex-5-mer-BME which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

boronic acid pinacol ester (1382734-63-5) + 1,4-dihexyl-2,5-diiodobenzene (162715-91-5) → hex-5-mer-BME (1382734-92-0)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride; In 1,4-dioxane; water; Inert atmosphere; Reflux;

DOI:10.1002/chem.201201985

Reference yield: 74.0%

→ hex-5-mer-BME (1382734-92-0)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium fluoride; In 1,4-dioxane; water;

Reference yield:

C23H21BrO3 (1382734-57-7) → hex-5-mer-BME (1382734-92-0)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium acetate; bis-triphenylphosphine-palladium(II) chloride / dimethyl sulfoxide / 14 h / 80 °C

2: cesium fluoride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane; water / Inert atmosphere; Reflux

With bis-triphenylphosphine-palladium(II) chloride; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; cesium fluoride; In 1,4-dioxane; water; dimethyl sulfoxide; 2: |Suzuki-Miyaura Coupling;

DOI:10.1002/chem.201201985

upstream raw materials:

methyl 4-iodosalicylate

C₂₃H₂₁BrO₃

boronic acid pinacol ester

1,4-dihexyl-2,5-diiodobenzene