(5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II)

Base Information

• Chemical Name: (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II)
• CAS No.: 817627-99-9
• Molecular Formula: C₄₈H₂₈N₄O₈Zn
• Molecular Weight: 854.162
• Mol file: 817627-99-9.mol

Synonyms:(5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II)

Chemical Property of (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II)

There total 6 articles about (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

C48H24N8Zn → (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II) (817627-99-9)

Guidance literature:

With water; sodium hydroxide; In ethanol; at 80 ℃; for 48h;

DOI:10.1016/j.poly.2016.06.002

Reference yield:

m-ZnTCPP-[E] (134980-27-1) + water (7732-18-5) → (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II) (817627-99-9)

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; sodium hydroxide; (N2); addn. of 2 N aqueous soln. of NaOH to soln. of porphyrin deriv. inTHF, stirring at room temp. for 3 d; evapn., extn. (CHCl3) to remove pristine compd., addn. of 1 N aqueous HCl to aqueous phase, filtration, washing with water and ether;

DOI:10.1021/ja068218u

Reference yield:

3,3′,3″,3?-(porphine-5,10,15,20-tetrayl)tetrakis(methylbenzoate) → (5,10,15,20-tetrakis(3-carboxyphenyl)porphyrinato)zinc(II) (817627-99-9)

Guidance literature:

Multi-step reaction with 2 steps

1: water; potassium hydroxide / tetrahydrofuran / Reflux; Darkness

2: zinc diacetate

With zinc diacetate; water; potassium hydroxide; In tetrahydrofuran;

DOI:10.1002/asia.201100533

upstream raw materials:

m-ZnTCPP-[E]

water

Methyl 3-formylbenzoate

5,10,15,20-tetrakis(3-carboxyphenyl)porphyrin