C₂₇H₁₆Br₂O₅

Base Information

Chemical Name:C₂₇H₁₆Br₂O₅
CAS No.:126629-18-3
Molecular Formula:C₂₇H₁₆Br₂O₅
Molecular Weight:580.229
Hs Code.:

C<sub>27</sub>H<sub>16</sub>Br<sub>2</sub>O<sub>5</sub>

Synonyms:C₂₇H₁₆Br₂O₅

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Chemical Property of C₂₇H₁₆Br₂O₅

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Technology Process of C₂₇H₁₆Br₂O₅

There total 12 articles about C₂₇H₁₆Br₂O₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: (Z)-(2S,9S,10R)-2,10-Dihydroxy-bicyclo[7.3.1]trideca-1⁽¹²⁾,5-diene-3,7-diyn-11-one

: 586-75-4
4-chlorobenzoyl chloride

: 126629-18-3
C₂₇H₁₆Br₂O₅

Guidance literature:: With TEA; In dichloromethane; 0 deg C to 25 deg C;
DOI:10.1016/S0040-4039(01)80649-3

Reference yield:

: 126629-11-6
(Z)-7-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyl]-hept-4-ene-2,6-diynal

: 126629-18-3
C₂₇H₁₆Br₂O₅

Guidance literature:: Multi-step reaction with 11 steps

1: 1.) n-BuLi, MgBr₂ / 1.) THF, -78 deg C

2: nBu₄NF / tetrahydrofuran / 0 °C

3: Et₃N / CH₂Cl₂ / 0 °C

4: 49 percent / CuI, TEA / Pd(CH₃CN)2Cl₂ / benzene

5: 40 percent / Kishi's radical inhibitor / benzene / 120 °C

6: 83 percent / K₂CO₃, H₂O / methanol

7: 73 percent

8: 91 percent / DDQ

9: Et₂AlCl / CH₂Cl₂ / -78 deg C to -20 deg C, 2 h

10: 79 percent / HF / acetonitrile

11: 65 percent / TEA / CH₂Cl₂ / 0 deg C to 25 deg C

With copper(l) iodide; n-butyllithium; Kishi's radical inhibitor; TEA; hydrogen fluoride; tetrabutyl ammonium fluoride; water; diethylaluminium chloride; potassium carbonate; triethylamine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; magnesium bromide; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; methanol; dichloromethane; acetonitrile; benzene;
DOI:10.1016/S0040-4039(01)80649-3

Reference yield:

: ((Z)-7,7-Diethoxy-hept-3-ene-1,5-diynyl)-dimethyl-(1,1,2-trimethyl-propyl)-silane

: 126629-18-3
C₂₇H₁₆Br₂O₅

Guidance literature:: Multi-step reaction with 12 steps

1: 85 percent / TFA/H₂O / CHCl₃ / Ambient temperature

2: 1.) n-BuLi, MgBr₂ / 1.) THF, -78 deg C

3: nBu₄NF / tetrahydrofuran / 0 °C

4: Et₃N / CH₂Cl₂ / 0 °C

5: 49 percent / CuI, TEA / Pd(CH₃CN)2Cl₂ / benzene

6: 40 percent / Kishi's radical inhibitor / benzene / 120 °C

7: 83 percent / K₂CO₃, H₂O / methanol

8: 73 percent

9: 91 percent / DDQ

10: Et₂AlCl / CH₂Cl₂ / -78 deg C to -20 deg C, 2 h

11: 79 percent / HF / acetonitrile

12: 65 percent / TEA / CH₂Cl₂ / 0 deg C to 25 deg C

With copper(l) iodide; n-butyllithium; Kishi's radical inhibitor; TEA; hydrogen fluoride; tetrabutyl ammonium fluoride; water; diethylaluminium chloride; potassium carbonate; triethylamine; trifluoroacetic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; magnesium bromide; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; methanol; dichloromethane; chloroform; acetonitrile; benzene;
DOI:10.1016/S0040-4039(01)80649-3