pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

Base Information

Chemical Name:pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane
CAS No.:18461-36-4
Molecular Formula:C₁₇H₁₀ClCrO₅P
Molecular Weight:412.686
Hs Code.:

pentacarbonylchromium<sup>(0)</sup> chlorodiphenylphosphane

Synonyms:pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

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Chemical Property of pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

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Technology Process of pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

There total 2 articles about pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 18461-36-4
pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

Guidance literature:: With tetrahydrofuran; In toluene; Irradiation (UV/VIS); (N2); soln. of Cr(CO)6 and THF was irradiated for 24 h, then a less than equimolar amt. of P-ligand in toluene was added dropwise and mixt. was stirred for a few h; major part of solvent was evapd. and residue chromd. (alumina, toluene), crystals are obtained by slow evapn. of the eluate in vac. at room temp.;
DOI:10.1016/0022-2860(80)85261-6

Reference yield:

: 15038-41-2
pentacarbonyl(tetrahydrofuran)chromium⁽⁰⁾

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 18461-36-4
pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

Guidance literature:: In not given; mole ratio of educts 1:1, inert solvent;;

Reference yield: 91.0%

: 18461-36-4
pentacarbonylchromium⁽⁰⁾ chlorodiphenylphosphane

: triethylammonium-pentacarbonyl(diphenylphosphinito-P)chrome⁽⁰⁾

Guidance literature:: With (C₂H₅)3N; In diethyl ether; water; byproducts: {HN(C2H5)3}Cl; a soln. of the educts (molar ratio complex : amine = 1.5:2) in water/ether 5:30 was stirred at 25 °C for 2 h until the bright yellow soln. had decolorized; reaction under protective gas in N2-satd. solvent;; after evapn. of solvent, the residue was washed free of chloride with water and dissolved in a small amt. of acetone, crystn. on cooling, recrystn. from Et2O); elem. anal.;;