(2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

Base Information

Chemical Name:(2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate
CAS No.:1312929-68-2
Molecular Formula:C₂₉H₃₀N₂O₆
Molecular Weight:502.567
Hs Code.:

Synonyms:(2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

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Chemical Property of (2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

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Technology Process of (2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

There total 3 articles about (2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 81167-39-7
methyl N-(diphenylmethylene)glycinate

: 3285-56-1
diethyl 2-(2-pyridylmethylidene)malonate

: 1312929-68-2
(2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

Guidance literature:: With C₃₆H₃₆FeN₃PS; silver(I) acetate; caesium carbonate; In tetrahydrofuran; at 20 ℃; for 2h; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/ol4019584

Reference yield:

: 81167-39-7
methyl N-(diphenylmethylene)glycinate

: 3285-56-1
diethyl 2-(2-pyridylmethylidene)malonate

: 1312929-68-2
(2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

: C₂₉H₃₀N₂O₆

Guidance literature:: With C₃₆H₃₆FeN₃PS; silver(I) acetate; In tetrahydrofuran; at 20 ℃; for 24h; Overall yield = 70 %; enantioselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1021/ol4019584

Reference yield:

: 81167-39-7
methyl N-(diphenylmethylene)glycinate

: 3285-56-1
diethyl 2-(2-pyridylmethylidene)malonate

: 1312929-68-2
(2S,3S)-1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

: 1,1-diethyl 3-methyl 3-(diphenylmethyleneamino)-2-(pyridin-2-yl)propane-1,1,3-tricarboxylate

Guidance literature:: With tetrakis(actonitrile)copper(I) hexafluorophosphate; (Rp)-2-(tert-butylthio)-1-(diphenyl-phosphino)ferrocene; caesium carbonate; In tetrahydrofuran; at 20 ℃; for 12h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201100374