iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂

Base Information

Chemical Name:iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂
CAS No.:84622-99-1
Molecular Formula:C₃₈H₃₀Br₂FeO₂P₂
Molecular Weight:796.258
Hs Code.:

iron(II)(carbonyl)2((phenyl)3phosphine)2Br<sub>2</sub>

Synonyms:iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂

Suppliers and Price of iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂

There total 11 articles about iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 36673-36-6,111408-20-9,14126-37-5,54053-52-0
dibromobis(triphenylphosphine)nickel(II)

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 51744-69-5,15020-31-2,84622-99-1
bis(triphenylphosphine)dicarbonyldibromoiron(II)

: 13007-90-4
bis(triphenylphosphine)nickel⁽⁰⁾ dicarbonyl

Guidance literature:: With triphenylphosphine; In tetrahydrofuran; byproducts: CO; addn. of excess Fe(CO)5 to equimolar mixt. of Ni-complex and PPh3, stirring (22°C, 18-20 h); evapn., chromy. (Al2O3, petroleum ether/benzene=1:1);
DOI:10.1016/S0020-1693(00)89590-0

Reference yield: 80.0%

: 18475-84-8
iron(II) carbonyl dibromide

: 14741-34-5,21255-52-7
tricarbonyl bis(triphenylphosphine) iron

: 84622-99-1
iron(II)(carbonyl)2((phenyl)3phosphine)2Br₂

Guidance literature:: With P(C₆H₅)3; In chloroform; Dissolving of Fe(CO)4Br2 and PPh3 in CHCl3 under N2 at room temp., immediate formation of Fe(CO)3(PPh3)Br2, transforms in 0.5 h, small quantities of Fe(CO)3(PPh3)2 also form.; Crystn. (n-hexane-CH2Cl2) yields Fe(CO)2(PPh3)2Br2, elem. anal.;

Reference yield: 45.0%

: 13463-40-6,37220-42-1
iron pentacarbonyl

: 13462-88-9
nickel dibromide

: 51744-69-5,15020-31-2,84622-99-1
bis(triphenylphosphine)dicarbonyldibromoiron(II)

: 13007-90-4
bis(triphenylphosphine)nickel⁽⁰⁾ dicarbonyl

Guidance literature:: With triphenylphosphine; In tetrahydrofuran; byproducts: CO; addn. of excess Fe(CO)5 to mixt. of NiBr2 and 3 equiv. PPh3, stirring (22°C, 18-20 h); evapn., chromy. (Al2O3, petroleum ether/benzene=1:1);
DOI:10.1016/S0020-1693(00)89590-0