Acetylene, 1-phenyl-2-trimethylgermyl-

Base Information

Chemical Name:Acetylene, 1-phenyl-2-trimethylgermyl-
CAS No.:4131-47-9
Molecular Formula:C11H14Ge
Molecular Weight:0
Hs Code.:2931900090
DSSTox Substance ID:DTXSID10194287
Nikkaji Number:J1.074.316H
Wikidata:Q83067053
Mol file:4131-47-9.mol

Synonyms:Acetylene, 1-phenyl-2-trimethylgermyl-;4131-47-9;DTXSID10194287

Suppliers and Price of Acetylene, 1-phenyl-2-trimethylgermyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Acetylene, 1-phenyl-2-trimethylgermyl-

Chemical Property:

Vapor Pressure:0.0924mmHg at 25°C
Boiling Point:231.9°C at 760 mmHg
Flash Point:85.5°C
PSA：0.00000
LogP:2.91550
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:220.0307282
Heavy Atom Count:12
Complexity:192

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Ge](C)(C)C#CC1=CC=CC=C1

Technology Process of Acetylene, 1-phenyl-2-trimethylgermyl-

There total 4 articles about Acetylene, 1-phenyl-2-trimethylgermyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1066-38-2
iodotrimethylgermane

: 536-74-3
phenylacetylene

: 4131-47-9
1-phenylethynyl(trimethyl)germanium

Guidance literature:: With [{Ir(μ-Cl)(CO)2}2]; N-ethyl-N,N-diisopropylamine; In toluene; at 80 ℃; for 24h; Schlenk technique; Inert atmosphere; Sealed tube;
DOI:10.1039/c4dt02290d

Reference yield: 73.0%

: 126086-83-7
C₆H₅C₂Ge(CH₃)2Br

: 4131-47-9
1-phenylethynyl(trimethyl)germanium

Guidance literature:: With methylmagnesium bromide; In diethyl ether; (Ar); drop a soln. of MeMgBr to a soln. of educt at 0°C; stirring for 30 min at 0°C and then for 3 h at 20°C; evapn. of solvent (vac.); distn. (vac.);
DOI:10.1016/0022-328X(89)85019-3

Reference yield: 45.0%

: 2290-59-7
1-trimethylsilyl-2-trimethylgermylacetylene

: 536-74-3
phenylacetylene

: 4131-47-9
1-phenylethynyl(trimethyl)germanium

: 2170-06-1
1-Phenyl-2-(trimethylsilyl)acetylene

Guidance literature:: With 18-crown-6 ether; cesium fluoride; In benzene; (Ar); addn. of CsF to a mixt. of phenylacetylene and 18-crown-6 in C6H6,stirring for 5 min, addn. of germanium compd., stirring at room temp. f or 5-7 h; filtration through SiO2 or Al2O3, evapn.;
DOI:10.1016/S0022-328X(01)01109-3