[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

Base Information

Chemical Name:[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester
CAS No.:494760-52-0
Molecular Formula:C₅₆H₇₂O₁₃
Molecular Weight:953.18
Hs Code.:

[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-<i>b</i>]naphthalen-9-yl ester

Synonyms:[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

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Chemical Property of [5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

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Technology Process of [5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

There total 29 articles about [5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 494760-41-7
C₆₂H₈₆O₁₃Si

: 494760-52-0
[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 20 ℃; for 3h;
DOI:10.1021/ja028726d DOI:10.1021/ja036984k

Reference yield:

: 494760-60-0
[(2R,3S,4aR,5S,7S,8aR,9aS,10aS)-5-Benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid ethyl ester

: 494760-52-0
[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

Guidance literature:: Multi-step reaction with 6 steps

1.1: 2,6-lutidine / CH₂Cl₂ / 2 h / 0 °C

2.1: 695 mg / LiAlH₄ / diethyl ether / 0.67 h / 0 °C

3.1: aq. KBr; TEMPO; NaClO / NaHCO₃ / CH₂Cl₂ / 0.33 h / 0 °C

4.1: 54 mg / 2-methyl-2-butene; NaClO₂; aq. NaH₂PO₄ / 2-methyl-propan-2-ol / 1 h / 20 °C

5.1: Et₃N; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 2 h / 40 °C

5.2: 90 percent / DMAP / toluene / 0.5 h / 40 °C

6.1: 99 percent / TBAF / tetrahydrofuran / 3 h / 20 °C

With 2,6-dimethylpyridine; 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite; sodium dihydrogenphosphate; lithium aluminium tetrahydride; 2-methyl-but-2-ene; 2,4,6-trichlorobenzoyl chloride; tetrabutyl ammonium fluoride; triethylamine; potassium bromide; sodium hydrogencarbonate; In tetrahydrofuran; diethyl ether; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja036984k

Reference yield:

: 494760-72-4
2-[(2R,3S,4aR,5S,7S,8aR,9aS,10aS)-5-Benzyloxy-7-(3-benzyloxy-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-ethanol

: 494760-52-0
[5-benzyloxy-7-(3-benzyloxy-propyl)-3-hydroxy-4a,10a-dimethyl-decahydro-1,8,10-trioxa-anthracen-2-yl]-acetic acid 9,10a-dimethyl-2-phenyl-8-vinyl-dodecahydro-1,3,5,7,11-pentaoxa-benzo[4,5]cyclohepta[1,2-b]naphthalen-9-yl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: aq. KBr; TEMPO; NaClO / NaHCO₃ / CH₂Cl₂ / 0.33 h / 0 °C

2.1: 54 mg / 2-methyl-2-butene; NaClO₂; aq. NaH₂PO₄ / 2-methyl-propan-2-ol / 1 h / 20 °C

3.1: Et₃N; 2,4,6-trichlorobenzoyl chloride / tetrahydrofuran / 2 h / 40 °C

3.2: 90 percent / DMAP / toluene / 0.5 h / 40 °C

4.1: 99 percent / TBAF / tetrahydrofuran / 3 h / 20 °C

With 2,2,6,6-tetramethyl-piperidine-N-oxyl; sodium hypochlorite; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; 2,4,6-trichlorobenzoyl chloride; tetrabutyl ammonium fluoride; triethylamine; potassium bromide; sodium hydrogencarbonate; In tetrahydrofuran; dichloromethane; tert-butyl alcohol;
DOI:10.1021/ja036984k