methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate

Base Information

Chemical Name:methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate
CAS No.:1404225-18-8
Molecular Formula:C₂₄H₃₉ClO₄Si₂
Molecular Weight:483.195
Hs Code.:

Synonyms:methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate

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Chemical Property of methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate

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Technology Process of methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate

There total 1 articles about methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 1003601-43-1
(Z)-((4-chloro-1-phenylbut-1-en-1-yl)oxy)trimethylsilane

: 166392-81-0
methyl 3-tert-butyldimethylsilyloxy-2-diazobut-3-enoate

: 1404225-18-8
methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate

Guidance literature:: (Z)-((4-chloro-1-phenylbut-1-en-1-yl)oxy)trimethylsilane; With 4C₂₀H₂₀NO₄^(1-)*2Rh⁽¹⁺⁾; at 20 ℃; Inert atmosphere;

methyl 3-tert-butyldimethylsilyloxy-2-diazobut-3-enoate; at 20 ℃; for 3h; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja3092399

Reference yield: 88.0%

: 1404225-18-8
methyl (S)-7-chloro-5-((R)-2,2,6,6,7,7-hexamethyl-4-phenyl-3,5-dioxa-2,6-disilaoctan-4-yl)hept-2-ynoate

: 1404225-19-9
methyl (S)-5-benzoyl-7-chlorohept-2-ynoate

Guidance literature:: With tris(dimethylamino)sulfonium trimethylsilyldifluoride; In N,N-dimethyl-formamide; at 0 ℃; for 0.05h; Inert atmosphere;
DOI:10.1021/ja3092399