(R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

Base Information

Chemical Name:(R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide
CAS No.:308246-06-2
Molecular Formula:C₂₅H₃₁NO₃SSe
Molecular Weight:504.552
Hs Code.:

Synonyms:(R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

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Chemical Property of (R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

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Technology Process of (R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

There total 5 articles about (R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1666-13-3
diphenyl diselenide

: 308245-96-7
(R)-N-[1'-(2-Furyl)-3'3'-dimethylbutyl]-N-[2-(p-tolylsulfonyloxy)ethyl]toluene-p-sulfonamide

: 308246-06-2
(R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

Guidance literature:: diphenyl diselenide; With sodium tetrahydroborate; In ethanol; for 0.5h;

(R)-N-[1'-(2-Furyl)-3'3'-dimethylbutyl]-N-[2-(p-tolylsulfonyloxy)ethyl]toluene-p-sulfonamide; In tetrahydrofuran; ethanol; for 5h; Further stages.; Heating;
DOI:10.1039/b003067h

Reference yield:

: 2987-16-8
3,3-dimethylbutyrylaldehyde

: 308246-06-2
(R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

Guidance literature:: Multi-step reaction with 5 steps

1.1: 75 percent / tetrahydrofuran / 2 h / Heating

2.1: 99 percent / LiAlH₄ / diethyl ether / 1.5 h / Heating

3.1: 69 percent / H₂; aq. TFA / Pd(OH)2 / methanol / 10 h

4.1: 79 percent / Et₃N / CH₂Cl₂ / 72 h / 20 °C

5.1: NaBH₄ / ethanol / 0.5 h

5.2: 85 percent / ethanol; tetrahydrofuran / 5 h / Heating

With sodium tetrahydroborate; lithium aluminium tetrahydride; hydrogen; triethylamine; trifluoroacetic acid; palladium dihydroxide; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; 1.1: Condensation / 2.1: Reduction / 3.1: Hydrogenolysis / 4.1: Substitution / 5.1: Reduction / 5.2: Substitution;
DOI:10.1039/b003067h

Reference yield:

: 182162-03-4
(5S,1'S)-N-[1'-(2-furyl)-3',3'-dimethylbutyl]-5-phenylmorpholin-2-one

: 308246-06-2
(R)-N-[1'-(2-Furyl)-3',3'-dimethylbutyl]-N-(2-phenylselenoethyl)toluene-p-sulfonamide

Guidance literature:: Multi-step reaction with 4 steps

1.1: 99 percent / LiAlH₄ / diethyl ether / 1.5 h / Heating

2.1: 69 percent / H₂; aq. TFA / Pd(OH)2 / methanol / 10 h

3.1: 79 percent / Et₃N / CH₂Cl₂ / 72 h / 20 °C

4.1: NaBH₄ / ethanol / 0.5 h

4.2: 85 percent / ethanol; tetrahydrofuran / 5 h / Heating

With sodium tetrahydroborate; lithium aluminium tetrahydride; hydrogen; triethylamine; trifluoroacetic acid; palladium dihydroxide; In methanol; diethyl ether; ethanol; dichloromethane; 1.1: Reduction / 2.1: Hydrogenolysis / 3.1: Substitution / 4.1: Reduction / 4.2: Substitution;
DOI:10.1039/b003067h