1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

Base Information

Chemical Name:1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene
CAS No.:404872-02-2
Molecular Formula:C₃₀H₅₄O₃Si₂
Molecular Weight:518.928
Hs Code.:

Synonyms:1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

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Chemical Property of 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

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Technology Process of 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

There total 1 articles about 1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: (4-n-hexylphenyl)magnesium bromide

: 201232-73-7
p-tert-butylphenyl 4,6-di-O-tert-butyl(dimethyl)silyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside

: 404872-02-2
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

Guidance literature:: With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; In tetrahydrofuran; at -40 ℃; for 24h;

Reference yield: 55.0%

: 404872-02-2
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

: 404872-08-8
1-(2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)-4-n-hexylbenzene

Guidance literature:: With tetrabutyl-ammonium chloride; In tetrahydrofuran; at 25 ℃; for 2h;

Reference yield:

: 404872-02-2
1-[4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]-4-n-hexylbenzene

: 404872-14-6
1-(2,3-dideoxy-β-D-erythro-hexanopyranosyl)-4-n-hexylbenzene

Guidance literature:: Multi-step reaction with 2 steps

1: 55 percent / tetrabutylammonium chloride trihydrate / tetrahydrofuran / 2 h / 25 °C

2: 80 percent / H₂ / [Rh(COD)(1,4-bis(diphenylphosphino)butane)]ClO₄ / ethanol / 24 h / 20 °C / atmospheric pressure

With tetrabutyl-ammonium chloride; hydrogen; [Rh(COD)(1,4-bis(diphenylphosphino)butane)]ClO₄; In tetrahydrofuran; ethanol;