8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

Base Information

Chemical Name:8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene
CAS No.:1360876-03-4
Molecular Formula:C₇₄H₉₈N₄
Molecular Weight:1043.62
Hs Code.:

Synonyms:8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

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Chemical Property of 8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

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Technology Process of 8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

There total 11 articles about 8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1360876-16-9
N,N'-bis(3-(4-(1,1-dimethylnonyl)-phenylamino)-4,6-diisopropylene-phenyl)-4-tertbutyl-2,6-diamino-biphenyl

: 1360876-03-4
8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

Guidance literature:: N,N'-bis(3-(4-(1,1-dimethylnonyl)-phenylamino)-4,6-diisopropylene-phenyl)-4-tertbutyl-2,6-diamino-biphenyl; With phosphoric acid; sulfuric acid; at 60 ℃; for 0.25h; Inert atmosphere;

With sodium hydroxide; In water; Cooling with ice;
DOI:10.1021/jo2025948

Reference yield:

: 1360876-10-3
4-nitro-(1,1-dimethylnonyl)benzene

: 1360876-03-4
8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

Guidance literature:: Multi-step reaction with 4 steps

1.1: iron; acetic acid / 20 °C

2.1: 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate; sodium t-butanolate / toluene / 90 °C / Inert atmosphere

3.1: tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate / toluene / 72 h / 100 °C / Inert atmosphere

4.1: phosphoric acid; sulfuric acid / 0.25 h / 60 °C / Inert atmosphere

4.2: Cooling with ice

With 1,1'-bis-(diphenylphosphino)ferrocene; tri-tert-butyl phosphine; phosphoric acid; sulfuric acid; palladium diacetate; iron; acetic acid; sodium t-butanolate; In toluene; 4.1: Friedel-Crafts reaction;
DOI:10.1021/jo2025948

Reference yield:

: 1360876-13-6
4'-tert-butyl-2,6-dibromobiphenyl

: 1360876-03-4
8-(4-tert-butylphenyl)-5,7,9,11,16,18,20,22-octahydro-16,16,18,18,20,20,22,22-octamethyl-2,14-bis-(1,1-dimethylnonyl)-5,7,9,11-tetraaza-nonacene

Guidance literature:: Multi-step reaction with 4 steps

1.1: palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate / toluene / 25 h / 120 °C

2.1: palladium 10% on activated carbon; ammonium formate / ethanol / 46 h / Reflux

3.1: tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate / toluene / 72 h / 100 °C / Inert atmosphere

4.1: phosphoric acid; sulfuric acid / 0.25 h / 60 °C / Inert atmosphere

4.2: Cooling with ice

With tri-tert-butyl phosphine; phosphoric acid; sulfuric acid; palladium 10% on activated carbon; ammonium formate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate; In ethanol; toluene; 4.1: Friedel-Crafts reaction;
DOI:10.1021/jo2025948