Technology Process of C19H14O2
There total 4 articles about C19H14O2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
chlorobis(ethylene)rhodium(I) dimer; potassium hydroxide; (1R,4R)-2,5-diphenylbicyclo[2.2.2]octa-2,5-diene;
In
1,4-dioxane; water;
at 90 ℃;
for 22h;
enantioselective reaction;
Inert atmosphere;
DOI:10.1002/asia.201403290
- Guidance literature:
-
With
(R)-(-)-5,5’-bis(diphenyl;phosphine)-2,2,2’,2’-tetrafluoro-4,4’-bi-1,3-benzodioxole; bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate;
In
1,4-dioxane;
at 45 ℃;
for 0.5h;
Inert atmosphere;
Glovebox;
- Guidance literature:
-
1-hydroxy-2-naphthyl styryl ketone;
With
sodium hydride;
In
chloroform; mineral oil;
Inert atmosphere;
With
N-(9-anthracenylmethyl)cinchoninium chloride;
In
chloroform; mineral oil;
at 22 ℃;
for 1h;
Optical yield = 71 %ee; enantioselective reaction;
Inert atmosphere;
DOI:10.1002/ejoc.201200838