2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene

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Chemical Name:2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene
CAS No.:306987-81-5
Molecular Formula:C₁₁H₁₂F₆O₂Si
Molecular Weight:318.291
Hs Code.:

Synonyms:2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene

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Chemical Property of 2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene

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Technology Process of 2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene

There total 1 articles about 2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 61550-02-5
(furan-2-yloxy)-trimethylsilane

: 692-50-2
hexafluoro-2-butyne

: 306987-81-5
2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene

Guidance literature:: In benzene; at 82 ℃; for 5h;
DOI:10.1021/ol0064359

Reference yield:

: 306987-81-5
2,3-di(trifluoromethyl)-1-trimethylsilyloxy-7-oxabicyclo[2.2.1]hepta-2,5-diene

: (+/-)-(2S,3R,4R)-2,3-di(trifluoromethyl)-4-hydroxycyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / H₂ / Pd/C / ethyl acetate / 15 h / 20 °C

2: 80 percent / HCl / tetrahydrofuran; H₂O / 0.17 h / 20 °C

With hydrogenchloride; hydrogen; palladium on activated charcoal; In tetrahydrofuran; water; ethyl acetate; 1: Catalytic hydrogenation / 2: Hydrolysis;
DOI:10.1021/ol0064359