Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

Base Information

Chemical Name:Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester
CAS No.:115694-25-2
Molecular Formula:C₂₉H₂₅F₃O₂Si
Molecular Weight:490.597
Hs Code.:

Synonyms:Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

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Chemical Property of Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

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Technology Process of Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

There total 4 articles about Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 115694-09-2
(E)-(R)-2-((R)-Methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-en-1-ol

: 115694-25-2
Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

Guidance literature:: With acetic anhydride; dmap;
DOI:10.1016/S0040-4039(00)80295-6

Reference yield:

: (R)-Dibromomethyl-methyl-naphthalen-2-yl-phenyl-silane

: 115694-25-2
Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 1.)LDA / 1.) THF, -78 gradC

2: 99 percent / dimethylformamide / 1 h / 120 °C

3: 1.) tert-butyllithium 2.) boron fluoride etherate / 1.) THF, -78 gradC 2.) THF, -78 gradC

4: 99 percent / Ac₂O / DMAP

With boron trifluoride diethyl etherate; tert.-butyl lithium; acetic anhydride; lithium diisopropyl amide; dmap; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)80295-6

Reference yield:

: (R)-(1,1-Dibromo-propyl)-methyl-naphthalen-2-yl-phenyl-silane

: 115694-25-2
Trifluoro-acetic acid (E)-(R)-2-((R)-methyl-naphthalen-1-yl-phenyl-silanyl)-1-phenyl-but-2-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / dimethylformamide / 1 h / 120 °C

2: 1.) tert-butyllithium 2.) boron fluoride etherate / 1.) THF, -78 gradC 2.) THF, -78 gradC

3: 99 percent / Ac₂O / DMAP

With boron trifluoride diethyl etherate; tert.-butyl lithium; acetic anhydride; dmap; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)80295-6