(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

Base Information

Chemical Name:(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester
CAS No.:138906-99-7
Molecular Formula:C₂₈H₃₈O₆S
Molecular Weight:502.672
Hs Code.:

Synonyms:(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

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Chemical Property of (2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

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Technology Process of (2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

There total 10 articles about (2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 26398-93-6,26995-94-8
(E)-β-methylthiopropenoic acid

: 131607-32-4
(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-2-hydroxy-3-(4-methoxy-benzyloxy)-propyl ester

: 138906-99-7
(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 ℃; for 49h;

Reference yield:

: 82402-15-1
oct-6-yn-1-ol

: 138906-99-7
(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / Li, liq. NH₃ / tetrahydrofuran / 2 h

2: 93 percent / Br₂, 1,2-bis(diphenylphosphino)ethane / CH₂Cl₂ / 0.67 h / Ambient temperature

3: 1) Li / 1) Et₂O, 0 deg C, 3h, 2) THF, -78 deg C, 1h

4: 72 percent / NaClO₂, KH₂PO₄, 2-methylbut-2-ene / 2-methyl-propan-2-ol / 20 h / Ambient temperature

5: 50 percent / DCC, DMAP / CH₂Cl₂ / 12 h / 0 °C

6: 92 percent / DCC, DMAP / CH₂Cl₂ / 49 h / 0 °C

With dmap; sodium chlorite; potassium dihydrogenphosphate; 2-methyl-but-2-ene; ammonia; bromine; lithium; dicyclohexyl-carbodiimide; 1,2-bis-(diphenylphosphino)ethane; In tetrahydrofuran; dichloromethane; tert-butyl alcohol;

Reference yield:

: 63768-12-7,67133-87-3
(E)-2-octenyl alcohol

: 138906-99-7
(2Z,4E,11E)-Trideca-2,4,11-trienoic acid (S)-3-(4-methoxy-benzyloxy)-2-((E)-3-methylsulfanyl-acryloyloxy)-propyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 93 percent / Br₂, 1,2-bis(diphenylphosphino)ethane / CH₂Cl₂ / 0.67 h / Ambient temperature

2: 1) Li / 1) Et₂O, 0 deg C, 3h, 2) THF, -78 deg C, 1h

3: 72 percent / NaClO₂, KH₂PO₄, 2-methylbut-2-ene / 2-methyl-propan-2-ol / 20 h / Ambient temperature

4: 50 percent / DCC, DMAP / CH₂Cl₂ / 12 h / 0 °C

5: 92 percent / DCC, DMAP / CH₂Cl₂ / 49 h / 0 °C

With dmap; sodium chlorite; potassium dihydrogenphosphate; 2-methyl-but-2-ene; bromine; lithium; dicyclohexyl-carbodiimide; 1,2-bis-(diphenylphosphino)ethane; In dichloromethane; tert-butyl alcohol;