4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

Base Information

Chemical Name:4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene
CAS No.:906098-33-7
Molecular Formula:C₃₅H₃₆O₅
Molecular Weight:536.668
Hs Code.:

Synonyms:4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

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Chemical Property of 4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

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Technology Process of 4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

There total 9 articles about 4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 906098-30-4
4-((3S,4R,5R,6S)-4,5,6-tri(benzyloxy)octa-1,7-dien-3-yl)-1,2-dimethoxybenzene

: 906098-33-7
4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

Guidance literature:: With dimethyl sulfoxide; Grubbs catalyst first generation; In dichloromethane;
DOI:10.1021/jo0607562

Reference yield:

: 906098-27-9
(3S,4R,5R,6S)-3-(3,4-dimethoxyphenyl)-4,5,6-tri(benzyloxy)-7-octen-1-ol

: 906098-33-7
4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

Guidance literature:: Multi-step reaction with 3 steps

1: Bu₃P / tetrahydrofuran

2: aq. H₂O₂ / tetrahydrofuran / 20 °C

3: 81 percent / DMSO / (Cy₃P)2(PhCH=)RuCl₂ / CH₂Cl₂

With tributylphosphine; dihydrogen peroxide; dimethyl sulfoxide; Grubbs catalyst first generation; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0607562

Reference yield:

: 906098-24-6
methyl (3S,4R,5R,6S)-3-(3,4-dimethoxyphenyl)-4,5,6-tri(benzyloxy)-7-octenoate

: 906098-33-7
4-((1S,4S,5R,6R)-4,5,6-tri(benzyloxy)cyclohex-2-enyl)-1,2-dimethoxybenzene

Guidance literature:: Multi-step reaction with 4 steps

1: LiAlH₄ / diethyl ether / 3 h / 0 - 20 °C

2: Bu₃P / tetrahydrofuran

3: aq. H₂O₂ / tetrahydrofuran / 20 °C

4: 81 percent / DMSO / (Cy₃P)2(PhCH=)RuCl₂ / CH₂Cl₂

With lithium aluminium tetrahydride; tributylphosphine; dihydrogen peroxide; dimethyl sulfoxide; Grubbs catalyst first generation; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1021/jo0607562