oxovanadium(V)trimesityl

Base Information

• Chemical Name: oxovanadium(V)trimesityl
• CAS No.: 82364-94-1
• Molecular Formula: C₂₇H₃₃OV
• Molecular Weight: 424.5
• Mol file: 82364-94-1.mol

Synonyms:oxovanadium(V)trimesityl

Chemical Property of oxovanadium(V)trimesityl

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of oxovanadium(V)trimesityl

There total 3 articles about oxovanadium(V)trimesityl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

[V(mesityl)3(THF)] (79738-18-4) → oxovanadium(V)trimesityl (82364-94-1)

Guidance literature:

With styrene oxide or OCH₂CHCH₂CH₃; In tetrahydrofuran; N2; soln. stirred for 30 min; concn. to drynesss, extn. with n-hexane, soln. obtained was filtered, concd., elem. anal.;

Reference yield: 83.0%

styrene oxide (96-09-3) + [V(mesityl)3(THF)] (79738-18-4) → oxovanadium(V)trimesityl (82364-94-1)

Guidance literature:

In tetrahydrofuran; byproducts: styrene; oxidn. of the vanadium complex in THF with styrene oxide at room temp.; crystn. (n-hexane);

DOI:10.1039/c39910000762

Reference yield: 66.0%

Li(1+)*VO(C6H2(CH3)3)3(1-)*3.25C4H8O = LiVO(C6H2(CH3)3)3(C4H8O)3.25 → oxovanadium(V)trimesityl (82364-94-1)

Guidance literature:

With C₆Cl₄O₂; In diethyl ether; byproducts: C6Cl4O2Li; (inert), V-complex stirred in the darkness with C6Cl4O2 in ether for at least 8 h at room temp.; left to stand overnight, filtered, cooled, pptn. removed, dried in vacuo, elem. anal.;

upstream raw materials:

styrene oxide

[V(mesityl)3(THF)]

Downstream raw materials:

bis(trimesitylvanadium)oxide

bimesityl

1,3,5-trimethyl-benzene

mesityl vanadium(V)oxiddichloride

Refernces

• 1、 Ruiz, Javier,Vivanco, Marilin,Floriani, Carlo,Chiesi-Villa, Angiola,Guastini, Carlo. "Oxovanadium(V) and Oxovanadium(IV) Organometallic Compounds from Direct Oxidation of the corresponding Vanadium(III) Precursors: the X-Ray Structure of Tris-mesityl Oxovanadium(V)". . p. 762 - 764. Retrieved 2007/10/02.