(1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

Base Information

Chemical Name:(1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane
CAS No.:152191-36-1
Molecular Formula:C₁₅H₂₀O₅S
Molecular Weight:312.387
Hs Code.:

Synonyms:(1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

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Chemical Property of (1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

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Technology Process of (1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

There total 8 articles about (1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 152191-32-7
1-((S)-6-Methoxymethoxy-cyclohex-1-enesulfonyl)-4-methyl-benzene

: 152191-36-1
(1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

Guidance literature:: With lithium tert-butyl hydroperoxide; In tetrahydrofuran; for 4h; Ambient temperature; or H₂O₂/NaOH, acetone, 45-50 deg C, 4 h;
DOI:10.1016/S0040-4039(00)74070-6

Reference yield:

: 140710-30-1
(S)-2-p-tolylsulfenyl-2-cyclohexenyl acetate

: 152191-36-1
(1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

Guidance literature:: Multi-step reaction with 4 steps

1: NaOH / methanol / Ambient temperature

2: 91 percent / MCPBA / CH₂Cl₂ / Ambient temperature

3: 90 percent / P₂O₅ / CHCl₃

4: 65 percent / LiOOt-Bu / tetrahydrofuran / 4 h / Ambient temperature; or H₂O₂/NaOH, acetone, 45-50 deg C, 4 h

With sodium hydroxide; lithium tert-butyl hydroperoxide; phosphorus pentoxide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)74070-6

Reference yield:

: 140710-34-5
(S)-2-p-Tolylsulfanyl-cyclohex-2-enol

: 152191-36-1
(1S,2S,6R)-2-Methoxymethoxy-1-(toluene-4-sulfonyl)-7-oxa-bicyclo[4.1.0]heptane

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / MCPBA / CH₂Cl₂ / Ambient temperature

2: 90 percent / P₂O₅ / CHCl₃

3: 65 percent / LiOOt-Bu / tetrahydrofuran / 4 h / Ambient temperature; or H₂O₂/NaOH, acetone, 45-50 deg C, 4 h

With lithium tert-butyl hydroperoxide; phosphorus pentoxide; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1016/S0040-4039(00)74070-6