methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

Base Information

Chemical Name:methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate
CAS No.:440641-43-0
Molecular Formula:C₃₂H₃₄O₇SSi
Molecular Weight:590.769
Hs Code.:

Synonyms:methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

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Technology Process of methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

There total 3 articles about methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 440640-95-9
methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-(4'-methoxybenzyloxy)butanoate

: 440641-43-0
methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 35 ℃; for 12h;
DOI:10.1021/jo011157s

Reference yield:

: 440641-41-8
(3R,4R)-4-tert-butyldiphenylsiloxy-3-(4-methoxybenzyloxy)dihydro-2(3H)-furanone

: 440641-43-0
methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / Cs₂CO₃ / 1 h / 0 °C

2: 95 percent / DCC; DMAP / CH₂Cl₂ / 12 h / 20 °C

3: DDQ / CH₂Cl₂; H₂O / 12 h / 35 °C

With dmap; caesium carbonate; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1021/jo011157s

Reference yield:

: 440640-93-7
methyl (2R,3R)-4-(tert-butyldiphenylsilyl)oxy-3-hydroxy-2-(4-methoxybenzyl)oxybutanoate

: 440641-43-0
methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-hydroxybutanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / DCC; DMAP / CH₂Cl₂ / 12 h / 20 °C

2: DDQ / CH₂Cl₂; H₂O / 12 h / 35 °C

With dmap; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water;
DOI:10.1021/jo011157s