dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

Base Information

• Chemical Name: dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium
• CAS No.: 37843-35-9
• Molecular Formula: C₄₂H₃₉Cl₂OP₃Ru
• Molecular Weight: 824.668

Synonyms:dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

Chemical Property of dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

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Technology Process of dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium

There total 6 articles about dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

[Ru(CO)2(1,1,1-tris(diphenylphosphinomethyl)ethane-κ2P)Cl2] (1222312-05-1,37843-36-0) → dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (37843-35-9)

Guidance literature:

In dichloromethane; The solution was kept aside for about two weeks.; The solvent was evapd. under reduced pressure; the product was washed with diethyl ether.;

DOI:10.1016/j.jorganchem.2010.01.011

Reference yield:

Ru(CF3SO3)(CO)2(CH3C(CH2P(C6H5)2)3)(1+)*CF3SO3(1-)={Ru(CF3SO3)(CO)2(CH3C(CH2P(C6H5)2)3)}(CF3SO3) (112220-44-7) + (C2H5)4N(1+)*Cl(1-)*2H2O=((C2H5)4N)Cl*2H2O → dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (37843-35-9) + tetraethylammonium trifluoromethanesulphonate (35895-69-3)

Guidance literature:

In dichloromethane; byproducts: CO; Ar atmosphere, 2 equiv. Et4NCl, stirring (30 min); evapn., recrystn. (acetone);

Reference yield:

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(0) (37843-33-7) → dichlorocarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium (37843-35-9) + chlorodicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium(1+) chloride (37843-36-0,1222312-05-1)

Guidance literature:

With CHCl₃; In chloroform; dissolution in CHCl3, 15 min; detected by IR;

upstream raw materials:

dicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽⁰⁾

Ru(CF₃SO₃)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)⁽¹⁺⁾*CF₃SO₃^(1-)={Ru(CF₃SO₃)(CO)2(CH₃C(CH₂P(C₆H₅)2)3)}(CF₃SO₃)

chlorodicarbonyl{1,1,1-tris((diphenylphosphino)methyl)ethane}ruthenium⁽¹⁺⁾ chloride

Ru(CO)2(CH₃C(CH₂P(C₆H₅)2)3)

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