(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

Base Information

Chemical Name:(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene
CAS No.:897672-22-9
Molecular Formula:C₅₉H₈₂F₆O₁₆S₂
Molecular Weight:1225.41
Hs Code.:

(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

Synonyms:(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

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Chemical Property of (S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

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Technology Process of (S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

There total 9 articles about (S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.5%

: 897672-29-6
(S)-3-bromo-5-[4-(2-{2-[2-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)ethoxy]ethoxy}-1-methylethoxy)phenyl]-2-methylthiophene

: 559-40-0
octaperfluorocyclopentene

: 897672-22-9
(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

Guidance literature:: (S)-3-bromo-5-[4-(2-{2-[2-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)ethoxy]ethoxy}-1-methylethoxy)phenyl]-2-methylthiophene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

octaperfluorocyclopentene; In tetrahydrofuran; hexane; at -78 ℃; for 1h;
DOI:10.1021/jo060505t

Reference yield:

: 897672-26-3
(S)-1-{2-[2-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)ethoxy]ethoxy}propan-2-ol

: 897672-22-9
(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

Guidance literature:: Multi-step reaction with 4 steps

1.1: 74.5 percent / aq. NaOH / tetrahydrofuran / 7 h / 20 °C

2.1: 100 percent / K₂CO₃ / dimethylformamide / 7 h / 70 °C

3.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

3.2: boric acid tri-n-butyl ester / tetrahydrofuran; hexane / 1 h / -78 °C

3.3: 39.5 percent / aq. Na₂CO₃ / Pd(PPh₃)4 / tetrahydrofuran; hexane / 12 h / Heating

4.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

4.2: 19.5 percent / tetrahydrofuran; hexane / 1 h / -78 °C

With sodium hydroxide; n-butyllithium; potassium carbonate; In tetrahydrofuran; hexane; N,N-dimethyl-formamide;
DOI:10.1021/jo060505t

Reference yield:

: 897672-28-5
(S)-p-iodo-(2-{2-[2-(2-{2-[2-(2-methoxyethoxy)ethoxy]ethoxy}ethoxy)ethoxy]ethoxy}propoxy)benzene

: 897672-22-9
(S,S)-1,2-bis[5-(4-{2-[2-(2-{2-[2-(2-{2-methoxyethoxy}ethoxy)ethoxy]ethoxy}ethoxy)ethoxy]-1-methylethoxy}phenyl)-2-methylthiophen-3-yl]perfluorocyclopentene

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

1.2: boric acid tri-n-butyl ester / tetrahydrofuran; hexane / 1 h / -78 °C

1.3: 39.5 percent / aq. Na₂CO₃ / Pd(PPh₃)4 / tetrahydrofuran; hexane / 12 h / Heating

2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 °C

2.2: 19.5 percent / tetrahydrofuran; hexane / 1 h / -78 °C

With n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.1021/jo060505t