cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂]

Base Information

• Chemical Name: cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂]
• CAS No.: 380613-02-5
• Molecular Formula: C₃₁H₄₀P₂Pt₂S
• Molecular Weight: 896.832
• Mol file: 380613-02-5.mol

Synonyms:cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂]

Chemical Property of cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂]

There total 1 articles about cis,cis-[Me₂Pt(μ-SMe₂)(μ-bis(diphenylphosphino)methane)PtMe₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Pt2Me4(μ-SMe2)2] (79870-64-7) + bis-diphenylphosphinomethane (2071-20-7) → cis,cis-[Me2Pt(μ-SMe2)(μ-bis(diphenylphosphino)methane)PtMe2] (380613-02-5)

Guidance literature:

In benzene; mixt. of Pt-complexes in benzene was stirred at room temp. for 3 h; solvent was removed, washed with MeOH, dried in vac.;

DOI:10.1016/S0022-328X(01)01057-9

Reference yield: 86.0%

cis,cis-[Me2Pt(μ-SMe2)(μ-bis(diphenylphosphino)methane)PtMe2] (380613-02-5) + 2-(diphenylphosphino)pyridine (37943-90-1) → cis,cis-[Me2(diphenylphosphinopyridine)Pt(μ-bis(diphenylphosphino)methane)Pt(diphenylphosphinopyridine)Me2]

Guidance literature:

In benzene; byproducts: SMe2; mixt. of Pt complex and P ligand (2 equiv.) in C6H6 was stirred at room temp. for 1 h; solvent removed (vac.); washed (hexane); dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2005.01.002

Reference yield: 65.0%

PHTHALAZINE (253-52-1) + cis,cis-[Me2Pt(μ-SMe2)(μ-bis(diphenylphosphino)methane)PtMe2] (380613-02-5) → cis-[Me2Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe2] (865186-98-7)

Guidance literature:

In acetone; to soln. Pt complex in acetone soln. phthalazine in acetone was added atroom temp. and stirred for 1 h; solvent was removed in vacuo, residue was triturated with ether, ppt. was dried in vacuo; elem. anal.;

DOI:10.1021/ic0511064

upstream raw materials:

[Pt2Me4(μ-SMe2)2]

bis-diphenylphosphinomethane

Downstream raw materials:

cis,cis-[Me2(P(O-i-Pr)3)Pt(μ-bis(diphenylphosphino)methane)Pt(P(O-i-Pr)3)Me2]

cis-[Me₂Pt(μ-phthalazine)(μ-bis(diphenylphosphino)methane)PtMe₂]